Tris[N,N,N,N-tetramethylguanidinium][tris(1S)-(1,1’-binaphalene)-2,2’-diolato]lanthanate La-HTMG-B|57-1250|1611526-71-6

Tris[N,N,N,N-tetramethylguanidinium][tris(1S)-(1,1’-binaphalene)-2,2’-diolato]lanthanate La-HTMG-B

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Sku SC57-1250_1_G
US-Strem
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Product Information

Product Name
TrisN,N,N,N-tetramethylguanidiniumtris(1S)-(1,1’-binaphalene)-2,2’-diolatolanthanate La-HTMG-B
Brand Name
US-Strem
Product Number
57-1250
CAS
1611526-71-6
Certificate of Analysis (COA)​
COA not found

General Information

PubChem CID
146012685
IUPAC Name
hydron;lanthanum(3+);tris(1-(2-oxidonaphthalen-1-yl)naphthalen-2-olate);1,1,3,3-tetramethylguanidine
InChI Key
WEYSBGPBUXFDFR-UHFFFAOYSA-I
SMILES
H+.CN(C)C(=N)N(C)C.C1=CC=C2C(=C1)C=CC(=C2C3=C(C=CC4=CC=CC=C43)O-)O-.C1=CC=C2C(=C1)C=CC(=C2C3=C(C=CC4=CC=CC=C43)O-)O-.C1=CC=C2C(=C1)C=CC(=C2C3=C(C=CC4=CC=CC=C43)O-)O-.La+3

Application

Technical Notes:
1.Catalyst used for an asymmetric Michael addition .
2.Catalyst used for an asymmetric Michael addition of 1 ,3-dicarbonyls to enones.
3.Catalyst used for the asymmetric aza-MichaeI addition of methylhydroxylamine to chalcone derivatives. 4.Catalyst used for the asymmetric direct aldol reaction
Reference:
1.J. Am. Chem. Soc., 2014, 136, 8034