Dimethylammonium dichlorotri(mu-chloro)bis[(R)-(+)-2,2'-bis(diphenylphosphino)-5,5',6,6',7,7',8,8'-octahydro-1,1'-binaphthyl]diruthenate(II) [NH2Me2][{RuCl((R)-H8-binap)}2(mu-Cl)3]|44-0516|2378771-65-2

Dimethylammonium dichlorotri(mu-chloro)bis[(R)-(+)-2,2'-bis(diphenylphosphino)-5,5',6,6',7,7',8,8'-octahydro-1,1'-binaphthyl]diruthenate(II) [NH2Me2][{RuCl((R)-H8-binap)}2(mu-Cl)3]

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Sku SC44-0516_250_MG
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Product Information

Product Name
Dimethylammonium dichlorotri(mu-chloro)bis(R)-(+)-2,2'-bis(diphenylphosphino)-5,5',6,6',7,7',8,8'-octahydro-1,1'-binaphthyldiruthenate(II) NH2Me2{RuCl((R)-H8-binap)}2(mu-Cl)3
Brand Name
US-Strem
Product Number
44-0516
CAS
2378771-65-2
Certificate of Analysis (COA)​
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Application

Technical Notes :
1. Biaryl bisphosphine ligand. The Ha-BINAP ligand, as the ruthenium complex, catalyzes hydrogenation of unsaturate carboxylic acids to a higher ee than does BINAP. (Ref. 1,2)
2. The ruthenium catalyzed hydrogenation of aryl propenoic acid to produce the drug lbuprofen.
References:
1. J. Org. Chem.. 1996. 61. 5510
2. Topics Organometal. Chem. 2004, 6. 63 (review).