Diacetato[(S)-(-)-2,2'-bis(diphenylphosphino)-5,5',6,6',7,7',8,8'-octahydro-1,1'-binaphthyl]ruthenium(II) Ru(OAc)2[(S)-H8-binap]|44-0167|142962-95-6

Diacetato[(S)-(-)-2,2'-bis(diphenylphosphino)-5,5',6,6',7,7',8,8'-octahydro-1,1'-binaphthyl]ruthenium(II) Ru(OAc)2[(S)-H8-binap]

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Product Information

Product Name
Diacetato(S)-(-)-2,2'-bis(diphenylphosphino)-5,5',6,6',7,7',8,8'-octahydro-1,1'-binaphthylruthenium(II) Ru(OAc)2(S)-H8-binap
Brand Name
US-Strem
Product Number
44-0167
CAS
142962-95-6
Certificate of Analysis (COA)​
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Application

Technical Notes:
1. Biaryl bisphosphine ligand. The Ha-BINAP ligand, as the ruthenium complex, catalyzes hydrogenation of unsaturated carboxylic acids to a higher ee than does BINAP. (Ref. 1,2)
2.The ruthenium catalyzed hydrogenation of aryl propenoic acid to produce the drug Ibuprofen.
References:
1. J. Org. Chem., 1996, 61, 5510.
2. Topics Organometal. Chem. 2004, 6, 63 (review).