Chloro[(R)-(+)-2,2'-bis(diphenylphosphino)-5,5',6,6',7,7',8,8'-octahydro-1,1'-binaphthyl](p-cymene)ruthenium(II) chloride [RuCl(p-cymene)((R)-H8-binap)]Cl|44-0094|944451-26-7

Chloro[(R)-(+)-2,2'-bis(diphenylphosphino)-5,5',6,6',7,7',8,8'-octahydro-1,1'-binaphthyl](p-cymene)ruthenium(II) chloride [RuCl(p-cymene)((R)-H8-binap)]Cl

$69.00

FREE
SHIPPING

100% MONEY
BACK GUARANTEE

ONLINE
SUPPORT 24/7

Available on backorder. No lead time available. Please request a quote.
Sku SC44-0094_50_MG
US-Strem
Get Bulk Quote

Product Information

Product Name
Chloro(R)-(+)-2,2'-bis(diphenylphosphino)-5,5',6,6',7,7',8,8'-octahydro-1,1'-binaphthyl(p-cymene)ruthenium(II) chloride RuCl(p-cymene)((R)-H8-binap)Cl
Brand Name
US-Strem
Product Number
44-0094
CAS
944451-26-7
Certificate of Analysis (COA)​
COA not found

Application

Technical Notes:
1.. Biary bisphosphine ligand. The Hg-BINAP ligand, as the ruthenium complex, catalyzes hydrogenation of unsaturated carboxylic acids to a higher ee than does BINAP. (Ref. 1,2)
2. The ruthenium catalyzed hydrogenation of aryl propenoic acid to produce the drug lbuprofen.
References:
1. J. Org. Chem., 1996, 61, 5510.
2.Topics Organometal. Chem. 2004, 6, 63 (review).