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Sku SC79-0352_1_G
US-Strem
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Product Information

Product Name
2-(Di-t-butylphosphino))-1,1'-biphenyl(acetonitrile)gold(I) hexafluoroantimonate, 99%
Brand Name
US-Strem
Product Number
79-0352
CAS
866641-66-9
Certificate of Analysis (COA)​
COA not found

General Information

PubChem CID
16689288
IUPAC Name
acetonitrile;ditert-butyl-(2-phenylphenyl)phosphane;gold(1+);hexafluoroantimony(1-)
InChI Key
ADQOZROJMVWPRI-UHFFFAOYSA-H
SMILES
CC#N.CC(C)(C)P(C1=CC=CC=C1C2=CC=CC=C2)C(C)(C)C.FSb-(F)(F)(F)(F)F.Au+

Application

Technical Notes:
1.Goid catalyst used in the regio -and stereoselective synthesis of functionalized benzoboxepines.
2.Gold catalyst used in the cyclization reactions of o-(buta-1.,3-diyn-1-yl-)-substituted N-aryl ureas
3.Gold catalyst used in the cycloisomerization of 1,7 -enyne esters to structurally diverse cis-tetrahydropyridin-4-ylketones
4.Catalyst used in the synthesis of coum arin- containing natural products.
5. Catalyst used in the synthesis of benzo4, 5imidazo1,2-aquinazolinones.
References:
1.Org. Lett, 2012, 14, 4742.
2.Org. Lett.,2013,15,2616
3.J. Org. Chem., 2013, 78, 3183. 4.J.Org.Chem.,2013,78,9876 5.J. Org. Chem., 2013, 78, 4312.

References Data Source From Pubchem

Introduction of Alk-1-enyl Groups

Publication Name: Science of Synthesis
Publication Date: 2024

Gold-Catalyzed Annulation

Publication Name: Science of Synthesis
Publication Date: 2023

Transition-Metal-Catalyzed[2 + 2]Cycloaddition

Publication Name: Science of Synthesis
Publication Date: 2022

Cyclopropanation with Methylene Catalytically Generated by Gold

Publication Name: Science of Synthesis
Publication Date: 2022

Allenes as Precursors of Aromatic Heterocycles

Publication Name: Science of Synthesis
Publication Date: 2022