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Sku SC77-9500_250_MG
US-Strem
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Product Information

Product Name
(Tricyclohexylphosphine)(1,5-cyclooctadiene)(pyridine)iridium(I)hexafluorophosphate, 99% CRABTREE'S CATALYST
Brand Name
US-Strem
Product Number
77-9500
CAS
64536-78-3
Certificate of Analysis (COA)​
COA not found

General Information

PubChem CID
5702647
IUPAC Name
(1Z,5Z)-cycloocta-1,5-diene;iridium;pyridine;tricyclohexylphosphane;hexafluorophosphate
InChI Key
WLRQNTYCIFESRH-KJWGIZLLSA-N
SMILES
C1CCC(CC1)P(C2CCCCC2)C3CCCCC3.C1/C=C\CC/C=C\C1.C1=CC=NC=C1.FP-(F)(F)(F)(F)F.Ir

Description

Technical Notes:
1.Iridium catalyst used for the highly enantioselective hydrogenation of a, ß-unsaturated esters.
2.Iridium catalyst used for the stereoselective catalytic hydrogenation and conjugate reduction of 4-
methylitaconate derivatives bearing a chiral auxiliary.
3.Iridium catalyst used in the synthesis of thiophene-based TAK-7 79 analogues via C-H arylation.
4.Iridium catalyst used in the practical synthetic approach to chiral (a-chloroalkyl)boronic esters via an iridium- catalyzed, chemoselective hydrogenation.
5.Iridium catalyst used in the regioselective C-H activation and hydrogen-isotope exchange of non-aromatic unsaturated functionality.

References Data Source From Pubchem

Hydrogen isotope labeling of PTC124

Publication Name: Radiochemistry
Publication Date: 2010-02
DOI: 10.1134/s1066362210010212