[(S)-(-)-5,5'-Bis(diphenylphosphino)-4,4'-bi-1,3-benzodioxole][4-cyano-3-nitrobenzenecarboxylato][1,2,3-η;-2-propenyl]iridium(III), min. 97%|77-5075|1221768-92-8

[(S)-(-)-5,5'-Bis(diphenylphosphino)-4,4'-bi-1,3-benzodioxole][4-cyano-3-nitrobenzenecarboxylato][1,2,3-η;-2-propenyl]iridium(III), min. 97%

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Sku SC77-5075_100_MG
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Product Information

Product Name
(S)-(-)-5,5'-Bis(diphenylphosphino)-4,4'-bi-1,3-benzodioxole4-cyano-3-nitrobenzenecarboxylato1,2,3-η;-2-propenyliridium(III), min. 97%
Brand Name
US-Strem
Product Number
77-5075
CAS
1221768-92-8
Certificate of Analysis (COA)​
COA not found

General Information

PubChem CID
156009271
IUPAC Name
4-cyano-3-nitrobenzene-6-ide-1-carboxylic acid;4-(5-diphenylphosphanyl-1,3-benzodioxol-4-yl)-1,3-benzodioxol-5-yl-diphenylphosphane;iridium;prop-1-ene
InChI Key
NORGVMHPLCHIQQ-UHFFFAOYSA-N
SMILES
CH2-C=C.C1OC2=C(O1)C(=C(C=C2)P(C3=CC=CC=C3)C4=CC=CC=C4)C5=C(C=CC6=C5OCO6)P(C7=CC=CC=C7)C8=CC=CC=C8.C1=C-C(=CC(=C1C#N)N+(=O)O-)C(=O)O.Ir

Application

Technical Notes:
1. Catalyst used for the diastereo- and enantioselective carbonyl (trimethylsilyl)allylation from the alcohol, or aldehyde, oxidation level.