Product Name
Di-μ-chlorobis(1,2,3-≈)-1-phenyl-2-propenyldipalladium(II), 98%
Certificate of Analysis (COA)
IUPAC Name
bis(palladium(2+));bis(prop-2-enylbenzene);dichloride
InChI Key
PHDNDSSMEIRHSI-UHFFFAOYSA-L
SMILES
C=CCH-C1=CC=CC=C1.C=CCH-C1=CC=CC=C1.Cl-.Cl-.Pd+2.Pd+2
Technlcal Notes:
1.Precursor for the preparation of a palladium catalyst used in the carbonylative arylation of ketones, yielding vinylbenzoate compounds.
2.Precursor for the preparation of a palladium catalyst used in the B uchwald-Hartwig amination of (hetero)aryI chlorides.
3.Precursor for the preparation of a palladium catalyst used in the arylative doaromatization of phenols.
4.Versatile palladium precursor for the preparation of palladium catalysts used in the cross-coupling of aryl chlorides and amines . conversion of aryl triflates to aryl fluorides. and the a-arylation of aldehydes .
References:
1.Chem. Eur. J.. 2012, 18. 1 5592.
2.Eur. J. Org- Chem., 2012, 3972.
3.J. Am. Chem. Soc., 2011. 133, 9282.
4.Chem. Eur. J.2010. 16, 1983.
5.Science, 2009. 325, 1661.
6.Org. Lett., 2008.10, 4561 .
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