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Sku SC45-2100_50_MG
US-Strem
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Product Information

Product Name
Tetrakis(R)-(+)-N-(p-dodecylphenylsulfonyl)prolinatodirhodium(II) Rh₂(R-DOSP)
Brand Name
US-Strem
Product Number
45-2100
CAS
178879-60-2
Certificate of Analysis (COA)​
COA not found

General Information

PubChem CID
11007799
IUPAC Name
tetrakis((2R)-1-(4-dodecylphenyl)sulfonylpyrrolidine-2-carboxylic acid);bis(rhodium)
InChI Key
IGTBJBHOQXYDMM-MSZWWGBCSA-N
SMILES
CCCCCCCCCCCCC1=CC=C(C=C1)S(=O)(=O)N2CCCC@@H2C(=O)O.CCCCCCCCCCCCC1=CC=C(C=C1)S(=O)(=O)N2CCCC@@H2C(=O)O.CCCCCCCCCCCCC1=CC=C(C=C1)S(=O)(=O)N2CCCC@@H2C(=O)O.CCCCCCCCCCCCC1=CC=C(C=C1)S(=O)(=O)N2CCCC@@H2C(=O)O.Rh.Rh

Description

Technical Notes:
1. Catalyst used for tandem asymmetric cyclopropanation/Cope rearrangement. 2. Catalyst used for an asymmetric 4 + 3 cycloaddition.
References:
1. Angew. Chem. Int. Ed., 2009, 48, 2398. 2. Org. L ett., 2008, 10, 573.

References Data Source From Pubchem

From Allylic Ethers

Publication Name: Science of Synthesis
Publication Date: 2008