(-)-4,5-Bis[(2R,5R)-2,5-dimethylphospholanyl](1,2-dimethyl-1,2-dihydropyridazine-3,6-dione)(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate, min. 95% [catASium? MNN(R)Rh]|45-0750|908128-78-9

(-)-4,5-Bis[(2R,5R)-2,5-dimethylphospholanyl](1,2-dimethyl-1,2-dihydropyridazine-3,6-dione)(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate, min. 95% [catASium? MNN(R)Rh]

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Product Information

Product Name
(-)-4,5-Bis(2R,5R)-2,5-dimethylphospholanyl(1,2-dimethyl-1,2-dihydropyridazine-3,6-dione)(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate, min. 95% catASium? MNN(R)Rh
Brand Name
US-Strem
Product Number
45-0750
CAS
908128-78-9
Certificate of Analysis (COA)​
COA not found

General Information

PubChem CID
71310603
IUPAC Name
4,5-bis(2R,5R)-2,5-dimethylphospholan-1-yl-1,2-dimethylpyridazine-3,6-dione;(1Z,5Z)-cycloocta-1,5-diene;rhodium;tetrafluoroborate
InChI Key
LZDNTTARCYFRIY-ZTCBNWEGSA-N
SMILES
B-(F)(F)(F)F.CC@H1P(C@@H(CC1)C)C2=C(C(=O)N(N(C2=O)C)C)P3C@@H(CCC@H3C)C.C1/C=C\CC/C=C\C1.Rh

Application

Technical Notes:
1.Highly enantioselective catalyst for the hydrogenation of E or z ß-acylamido acrylates under mild conditions and low pressure .
2.Highly enantioselective for the hyd rogenation of itaconates at room temperature.
References:
1.J. Org. Chem., 2003, 68, 1701.
2. Adv. Synth. Catal., 2004, 346, 1263.