Product Name
1,5-Cyclooctadiene(hydroquinone)rhodium(I) tetrafluoroborate
Certificate of Analysis (COA)
IUPAC Name
benzene-1,4-diol;(1Z,5Z)-cycloocta-1,5-diene;rhodium;tetrafluoroborate
InChI Key
AZTYAQCGFXPPHA-PHFPKPIQSA-N
SMILES
B-(F)(F)(F)F.C1/C=C\CC/C=C\C1.C1=CC(=CC=C1O)O.Rh
Technical Notes:
1. A phosphorous free pre catalyst for the efficient 1 ,4 conjugate addition of arylboronic acids to enones.
2.A pre catalyst for addition of arylboronic acids to ary! aldehydes.
3.With aluminum isopropoxide forms a self-supported heterog eneous catalyst for the stereoselective polymerization of phenylacetylene to cis-poly(phenylacetylene). (Ref. 3
References:
1.Organometallics, 2006, 25, 3548.
2.J. Am. Chem. Soc., 2005, 127, 12238.
3.J. Am. Chem. Soc., 2006, 128, 8740.