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Sku SC45-0110_2_G
US-Strem
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Product Information

Product Name
Bis(1,5-cyclooctadiene)rhodium(I) trifluoromethanesulfonate, 99%
Brand Name
US-Strem
Product Number
45-0110
CAS
99326-34-8
Certificate of Analysis (COA)​
COA not found

General Information

PubChem CID
5702638
IUPAC Name
bis((1Z,5Z)-cycloocta-1,5-diene);rhodium;trifluoromethanesulfonate
InChI Key
VUTUHLLWFPRWMT-QMDOQEJBSA-M
SMILES
C1/C=C\CC/C=C\C1.C1/C=C\CC/C=C\C1.C(S(=O)(=O)O-)(F)(F)F.Rh

Safety Information

Storage Condition
Store at 2-8℃

Description

Technical Notes:
1.Rhodium catalyzed contrasteric regiocontrolled hydrogenative couplings of nonsymmetric 1,3 diynes to ethyl glyoxalate 2.Rhodium catalyzed reductive Mannich coupling of vinyl ketones to N-Sulfonylimines mediated by hydrogen
3.Rhodium catalyzed asymmetric synthesis of Sitagliptin
4.Rhodium catalyzed asymmetric hydrogenation of tetrasubstituted a, ß unsaturated ketones
References:
1.Organometallics, 2007. 26, 3860.
2.J. Org. Chem., 2007. 72, 5843.
3.J.Am. Chem. Soc.. 2009, 131, 8798.
4.Org. Lott, 2012, 14. 1038.

References Data Source From Pubchem

Alkenylation

Publication Name: Science of Synthesis
Publication Date: 2024

Synthesis from Diynes and Ethyl Glyoxalate

Publication Name: Science of Synthesis
Publication Date: 2023

Synthesis from Diynes and α-Oxo Aldehydes

Publication Name: Science of Synthesis
Publication Date: 2023

Synthesis from Enynes and α-Oxo Aldehydes

Publication Name: Science of Synthesis
Publication Date: 2023

Synthesis from Enynes and Aldehydes

Publication Name: Science of Synthesis
Publication Date: 2023