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Product Information

Product Name
Bis(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate, 98+%
Brand Name
US-Strem
Product Number
45-0109
CAS
35138-22-8
Certificate of Analysis (COA)​
COA not found

General Information

PubChem CID
5702662
IUPAC Name
bis((1Z,5Z)-cycloocta-1,5-diene);rhodium;tetrafluoroborate
InChI Key
LYXHWHHENVLYCN-QMDOQEJBSA-N
SMILES
B-(F)(F)(F)F.C1/C=C\CC/C=C\C1.C1/C=C\CC/C=C\C1.Rh

Description

Technical Notes:
1.Convenient catalyst precursor, for example, with (R,R)QuinoxP* for asymmetric alkylations and hydrogenations . 2. Catalyst precursor with chiral biaryl bisphosphine ligands for (2+2+2 enantioenriched cycloadditions .
References:
1.See 15-0126
2.Angew. Chem, nt. Ed., 2009, 48, 5470.
3.Tetrahedron, 2009. 65, 5001.

References Data Source From Pubchem

Preparation of meta-cyclophanes via stereospecific ring-expansion rearrangement

Publication Name: Nature Synthesis
Publication Date: 2026-03-02
DOI: 10.1038/s44160-026-01016-5

Chelate complexes of PdII, RhI, and PtII with P*,P-bidentate phosphine-bicyclophosphoramidite

Publication Name: Russian Chemical Bulletin
Publication Date: 2025-08
DOI: 10.1007/s11172-025-4739-7

Rh-catalysed enantioselective [2+2+1] cycloaddition reactions using three different 2π-components

Publication Name: Nature Synthesis
Publication Date: 2024-07-17
DOI: 10.1038/s44160-024-00604-7

Modern Trends in the Synthesis of Disulfides: From Metal-Containing Catalysts to Nonmaterial Reagents (Review)

Publication Name: Russian Journal of Coordination Chemistry
Publication Date: 2023-12
DOI: 10.1134/s1070328423600985

Catalytic stereoselective synthesis of doubly, triply and quadruply twisted aromatic belts

Publication Name: Nature Synthesis
Publication Date: 2023-05-22
DOI: 10.1038/s44160-023-00318-2