Dichloro[(4S,5S)-(+)-4,5-bis(diphenylphosphinomethyl)-2,2-dimethyl-1,3-dioxolane][(S)-(-)-2-(i-propyl)methanamine)-1H-benzimidazole]ruthenium(II), min. 95%|44-0965|1443051-97-5

Dichloro[(4S,5S)-(+)-4,5-bis(diphenylphosphinomethyl)-2,2-dimethyl-1,3-dioxolane][(S)-(-)-2-(i-propyl)methanamine)-1H-benzimidazole]ruthenium(II), min. 95%

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Product Information

Product Name
Dichloro(4S,5S)-(+)-4,5-bis(diphenylphosphinomethyl)-2,2-dimethyl-1,3-dioxolane(S)-(-)-2-(i-propyl)methanamine)-1H-benzimidazoleruthenium(II), min. 95%
Brand Name
US-Strem
Product Number
44-0965
CAS
1443051-97-5
Certificate of Analysis (COA)​
COA not found

General Information

PubChem CID
121234192
IUPAC Name
(1S)-1-(1H-benzimidazol-2-yl)-2-methylpropan-1-amine;dichlororuthenium;(4S,5S)-5-(diphenylphosphanylmethyl)-2,2-dimethyl-1,3-dioxolan-4-ylmethyl-diphenylphosphane
InChI Key
QSACDIOLKHLTFP-RVHSTDQRSA-L
SMILES
CC(C)C@@H(C1=NC2=CC=CC=C2N1)N.CC1(OC@@H(C@H(O1)CP(C2=CC=CC=C2)C3=CC=CC=C3)CP(C4=CC=CC=C4)C5=CC=CC=C5)C.ClRuCl

Application

Technical Note:
1. Efficient ruthenium catalyst for asymmetric hydrogenation of aryl ketones. References： 1.Adv. Synth. Catal., 2011, 353, 495. 2.Org. L ett., 2009, 1 1, 907.