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Chlorocarbonylhydrido[4,5-bis-(di-i-propylphosphinomethyl)acridine]ruthenium(II), min.98% Milstein Acridine Catalyst|44-0525|1101230-25-4

Chlorocarbonylhydrido[4,5-bis-(di-i-propylphosphinomethyl)acridine]ruthenium(II), min.98% Milstein Acridine Catalyst

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Sku SC44-0525_25_MG
US-Strem
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Product Information

Product Name
Chlorocarbonylhydrido4,5-bis-(di-i-propylphosphinomethyl)acridineruthenium(II), min.98% Milstein Acridine Catalyst
Brand Name
US-Strem
Product Number
44-0525
CAS
1101230-25-4
Certificate of Analysis (COA)​
COA not found

General Information

PubChem CID
58320611
IUPAC Name
carbon monoxide;chlororuthenium;5-di(propan-2-yl)phosphaniumylmethylacridin-4-ylmethyl-di(propan-2-yl)phosphanium
InChI Key
DZDSPHJNBCABNT-UHFFFAOYSA-O
SMILES
CC(C)PH+(CC1=CC=CC2=C1N=C3C(=C2)C=CC=C3CPH+(C(C)C)C(C)C)C(C)C.C-#O+.ClRu

Description

Technical Notes:
1.Useful ruthenium catalyst for the direct conversion of alcohols to acetals and esters.
3.Useful ruthenium catalyst for the selective synthesis of amines directly from alcohols and ammonia. 3.Catalyst used in the direct amination of primary amines by water to produce alcohols.
References:
1. J. Am. Chem. Soc., 2009, 131, 3146. 2.Angew. Chem. Int. Ed., 2008, 47, 8661. 3.Angew. Chem. Int. Ed., 2013, 52, 6269.