Dimethylammonium dichlorotri(mu-chloro)bis{(R)-(+)-5,5'-bis[di(3,5-xylyl)phosphino]-4,4'-bi-1,3-benzodioxole}diruthenate(II) [NH2Me2][{RuCl((R)-dm-segphos?)}2(mu-Cl)3]|44-0520|935449-46-0

Dimethylammonium dichlorotri(mu-chloro)bis{(R)-(+)-5,5'-bis[di(3,5-xylyl)phosphino]-4,4'-bi-1,3-benzodioxole}diruthenate(II) [NH2Me2][{RuCl((R)-dm-segphos?)}2(mu-Cl)3]

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Sku SC44-0520_1_G
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Product Information

Product Name
Dimethylammonium dichlorotri(mu-chloro)bis{(R)-(+)-5,5'-bisdi(3,5-xylyl)phosphino-4,4'-bi-1,3-benzodioxole}diruthenate(II) NH2Me2{RuCl((R)-dm-segphos?)}2(mu-Cl)3
Brand Name
US-Strem
Product Number
44-0520
CAS
935449-46-0
Certificate of Analysis (COA)​
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Application

Technical Notes:
1. Biaryl bisphosphine ligand with narrow dihedral angle. The DM-S EGPHOS® ligand, as the ruthenium complex, gives superior
enantioselectivity and diastereoselectivity in the asymmetric hydrogenation of a-substituted-ß-ketoesters. See 15-0066.
2.Ruthenium catalyzed enantioselective synthesis of ß amino acids by hydrogenation
3.Ruthenium catalyzed asymmetric hydrogenation of 3-quinuclidinone. See 44-0098 for Ru catalyst.
References:
1. U.S. Pat. 7626034. 2. U.S. Pat 7462722.