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Dimethylammonium dichlorotri(μ-chloro)bis[(S)-(-)-5,5'-bis(diphenylphosphino)-4,4'-bi-1,3-benzodioxole]diruthenate(II) [NH₂Me₂][{RuCl((S)-segphos®)}₂(μ-Cl)₃]|44-0519|488809-34-3

Dimethylammonium dichlorotri(μ-chloro)bis[(S)-(-)-5,5'-bis(diphenylphosphino)-4,4'-bi-1,3-benzodioxole]diruthenate(II) [NH₂Me₂][{RuCl((S)-segphos®)}₂(μ-Cl)₃]

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Sku SC44-0519_5_G
US-Strem
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Product Information

Product Name
Dimethylammonium dichlorotri(μ-chloro)bis(S)-(-)-5,5'-bis(diphenylphosphino)-4,4'-bi-1,3-benzodioxolediruthenate(II) NH₂Me₂{RuCl((S)-segphos®)}₂(μ-Cl)₃
Brand Name
US-Strem
Product Number
44-0519
CAS
488809-34-3
Certificate of Analysis (COA)​
COA not found

General Information

PubChem CID
71310555
IUPAC Name
bis(4-(5-diphenylphosphanyl-1,3-benzodioxol-4-yl)-1,3-benzodioxol-5-yl-diphenylphosphane);N-methylmethanamine;ruthenium;trichloronioruthenium(1-);chloride;hydrochloride
InChI Key
GTKMQYLNAZIAEF-UHFFFAOYSA-M
SMILES
CNC.C1OC2=C(O1)C(=C(C=C2)P(C3=CC=CC=C3)C4=CC=CC=C4)C5=C(C=CC6=C5OCO6)P(C7=CC=CC=C7)C8=CC=CC=C8.C1OC2=C(O1)C(=C(C=C2)P(C3=CC=CC=C3)C4=CC=CC=C4)C5=C(C=CC6=C5OCO6)P(C7=CC=CC=C7)C8=CC=CC=C8.Cl.Cl-.ClH+Ru-(ClH+)ClH+.Ru

Description

Technical Notes:
1. Highly enantioselective, highly active catalyst for hydrogenation of functionalized ketones. The chlororuthenate salts show catalytic activity at relatively low temperature. See 15-0136.
2.Catalyst for enantioselective hydrogenation of enamines.
References:
1.Adv. Synth. Catal., 2001, 343, 264. 2.U.S. Pat. 8188307.