Dichloro{(R)-(+)-5,5'-bis[di(3,5-xylyl)phosphino]-4,4'-bi-1,3-benzodioxole}[(1R,2R)-(+)-1,2-diphenylethylenediamine]ruthenium(II) RuCl2[(R)-dm-segphos?][(R,R)-dpen]|44-0228|944450-45-7

Dichloro{(R)-(+)-5,5'-bis[di(3,5-xylyl)phosphino]-4,4'-bi-1,3-benzodioxole}[(1R,2R)-(+)-1,2-diphenylethylenediamine]ruthenium(II) RuCl2[(R)-dm-segphos?][(R,R)-dpen]

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Sku SC44-0228_5_G
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Product Information

Product Name
Dichloro{(R)-(+)-5,5'-bisdi(3,5-xylyl)phosphino-4,4'-bi-1,3-benzodioxole}(1R,2R)-(+)-1,2-diphenylethylenediamineruthenium(II) RuCl2(R)-dm-segphos?(R,R)-dpen
Brand Name
US-Strem
Product Number
44-0228
CAS
944450-45-7
Certificate of Analysis (COA)​
COA not found

General Information

PubChem CID
91972076
IUPAC Name
4-5-bis(3,5-dimethylphenyl)phosphanyl-1,3-benzodioxol-4-yl-1,3-benzodioxol-5-yl-bis(3,5-dimethylphenyl)phosphane;(1R,2R)-1,2-diphenylethane-1,2-diamine;ruthenium(2+);dichloride
InChI Key
FOEKPXQPRAIJRW-ODQAEMFESA-L
SMILES
CC1=CC(=CC(=C1)P(C2=C(C3=C(C=C2)OCO3)C4=C(C=CC5=C4OCO5)P(C6=CC(=CC(=C6)C)C)C7=CC(=CC(=C7)C)C)C8=CC(=CC(=C8)C)C)C.C1=CC=C(C=C1)C@H(C@@H(C2=CC=CC=C2)N)N.Cl-.Cl-.Ru+2

Application

Technical Notes:
1. Efficient catalyst for asymmetric hydrogenation of simple ketones.