Diacetato[(S)-(-)-5,5'-bis(diphenylphosphino)-4,4'-bi-1,3-benzodioxole]ruthenium(II) Ru(OAc)2[(S)-segphos?]|44-0169|373650-12-5

Diacetato[(S)-(-)-5,5'-bis(diphenylphosphino)-4,4'-bi-1,3-benzodioxole]ruthenium(II) Ru(OAc)2[(S)-segphos?]

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Sku SC44-0169_1_G
US-Strem
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Product Information

Product Name
Diacetato(S)-(-)-5,5'-bis(diphenylphosphino)-4,4'-bi-1,3-benzodioxoleruthenium(II) Ru(OAc)2(S)-segphos?
Brand Name
US-Strem
Product Number
44-0169
CAS
373650-12-5
Certificate of Analysis (COA)​
COA not found

General Information

PubChem CID
71310596
IUPAC Name
acetic acid;4-(5-diphenylphosphanyl-1,3-benzodioxol-4-yl)-1,3-benzodioxol-5-yl-diphenylphosphane;ruthenium
InChI Key
OISNHBFITMBIMI-UHFFFAOYSA-N
SMILES
CC(=O)O.CC(=O)O.C1OC2=C(O1)C(=C(C=C2)P(C3=CC=CC=C3)C4=CC=CC=C4)C5=C(C=CC6=C5OCO6)P(C7=CC=CC=C7)C8=CC=CC=C8.Ru

Application

Technical Notes:
1. Highly active highly enantioselective catalyst for hydrogenation of functionalized ketones. The acetate salts are frequently used for hydrogenation of allyl alcohols, unsaturated carboxylic acids and reductive amination. See 15-0136.
2. Asymmetric hydrogenation of substituted allyl alcohols.
Reference:
1. U.S. Pat. 6342644.