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Sku SC42-0575_10_PC
US-Strem
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Product Information

Product Name
2,6-Bis(1-methylethyl)benzenaminato(2-)bis(1,1,1,3,3,3-hexafluoro-2-methyl-2-propanolato-κO)(2-methyl-2-phenylpropylidene)-, (T-4) molybdenum, paraffin pellet
Brand Name
US-Strem
Product Number
42-0575
CAS
139220-25-0
Certificate of Analysis (COA)​
COA not found

General Information

PubChem CID
10996321
IUPAC Name
2,6-di(propan-2-yl)phenylimino-(2-methyl-2-phenylpropylidene)molybdenum;bis(1,1,1,3,3,3-hexafluoro-2-methylpropan-2-ol)
InChI Key
SKVDWEMQFYIDCB-UHFFFAOYSA-N
SMILES
CC(C)C1=C(C(=CC=C1)C(C)C)N=Mo=CC(C)(C)C2=CC=CC=C2.CC(C(F)(F)F)(C(F)(F)F)O.CC(C(F)(F)F)(C(F)(F)F)O

Safety Information

Storage Condition
Store at 2-8℃

Description

Technical Notes:
1.General metathesis of many ordinary olefins, especially terminal olefins, and will R MP many norbornene or substituted norbornadiene monomers to give all cis, and often isotactic, polymers.
2.Useful for the "ring-closing" of dienes or the coupling of te rminal olefins .
3.Highly active and most commonly used in cross metathesis of aliphatic alkenes with 2-vinyl aromatics .
References:
1.J. Am.Chem.Soc.,1994, 116, 3414.
2.J. Am.Chem.Soc.,1993, 1 15, 4413.
3.J.Am. Chem. Soc., 1992, 114, 5426.
4.J. Am. Chem. Soc.. 1992, 114, 7324.
5.Tetrahedron, 1998, 54, 4413. (review article ) 6.J. Mol. Catal. Chem., 2002, 190, 45.

References Data Source From Pubchem

Ring-Closing Metathesis

Publication Name: Science of Synthesis
Publication Date: 2021

Concise Seven-Membered Oxepene/Oxepane Synthesis – Structural Motifs in Natural and Synthetic Products

Publication Name: Synthesis
Publication Date: 2019-05-20
DOI: 10.1055/s-0037-1611838

Recent Advances in Total Synthesis via Metathesis Reactions

Publication Name: Synthesis
Publication Date: 2018-07-18
DOI: 10.1055/s-0037-1610206

Ring-Closing Metathesis with 1,n-Dienes

Publication Name: Science of Synthesis
Publication Date: 2016

E/Z Selectivity for Small and Medium Rings

Publication Name: Science of Synthesis
Publication Date: 2016