Chloro(4-cyanophenyl){(R)-1-[(S)-2-(dicyclohexylphosphino)ferrocenyl]ethyl (dicyclohexylphosphine)}nickel(II)|28-0172|2049086-35-1

Chloro(4-cyanophenyl){(R)-1-[(S)-2-(dicyclohexylphosphino)ferrocenyl]ethyl (dicyclohexylphosphine)}nickel(II)

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Sku SC28-0172_100_MG
US-Strem
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Product Information

Product Name
Chloro(4-cyanophenyl){(R)-1-(S)-2-(dicyclohexylphosphino)ferrocenylethyl (dicyclohexylphosphine)}nickel(II)
Brand Name
US-Strem
Product Number
28-0172
CAS
2049086-35-1
Certificate of Analysis (COA)​
COA not found

Application

Technical Notes:
1.Versatile, air-stable, low cost nickel catalyst alternative to palladium for carbon-carbon and carbon- heteroatom cross-coupling reactions .
2.Used to react substituted aryl and heteroaryl halides and tosylates with ammonia to produce diverse aryl and heteroaryl amines
3.Used in monoarylation experiments using commercially available ammonia gas, ammonium salts or ammonia stock solutions
4.Catalyzes the coupling of aryl chlorides with gaseous amines in the form of their hydrochloride salts
References:
1Org.Process Res. Dev., 2015, 19, 1936.
2.Angew. Chem, Int. Ed., 2015, 54, 3773. 3.Angew. Chem, Int. Ed., 2015, 54, 3768.