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Sku SC28-0095_25_G
US-Strem
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Product Information

Product Name
Bis(triphenylphosphine)nickel(II) chloride, 99%
Brand Name
US-Strem
Product Number
28-0095
CAS
14264-16-5
Certificate of Analysis (COA)​
COA not found

General Information

PubChem CID
498315
IUPAC Name
dichloronickel;bis(triphenylphosphane)
InChI Key
ZBRJXVVKPBZPAN-UHFFFAOYSA-L
SMILES
C1=CC=C(C=C1)P(C2=CC=CC=C2)C3=CC=CC=C3.C1=CC=C(C=C1)P(C2=CC=CC=C2)C3=CC=CC=C3.ClNiCl

Description

Technical Notes:
1. Catalyst for hydrosilylation of styrene with diphenysilane .
2.Catalyst for carboxylation of various aryl chlorides and other derivatives .
3.Catalyst for C-P cross-coupling reactions of diphenylphosphine oxide with aryl chloride.
4. Catalyst for N- Heterocyclic carbene-assisted cross-coupling reactions of diarylborinic acids with aryl chlorides,
tosylates, and sulfamates.
5.Catalyst for Negishi biaryl ketone synthesis by cross-coupling of amides with aryl zinc halides via carbon-nitrogen bond cleavage .
References:
1. Org. Lett., 2012, 14, 914.
2. J. Am. Chem. Soc., 2012, 134, 9106. 3. Org. Biomol. Chem., 2012,10, 9627. 4. J. Org. Chem., 2014, 79, 7132.
5. Chem. Eur. J., 2016, 22, 10420.

References Data Source From Pubchem

Chemoselective Synthesis of α-Ketoamines from α-Diketones and Arylamines Using Palladium and Rhodium Catalyst

Publication Name: Russian Journal of Coordination Chemistry
Publication Date: 2025-08
DOI: 10.1134/s1070328425600755

Nickel-catalyzed C(sp2)−C(sp3) cross-coupling to access benzyl Bpins of arylboronic acids with α-halo boronic esters

Publication Name: Communications Chemistry
Publication Date: 2025-05-06
DOI: 10.1038/s42004-025-01539-6

Group 10 Molecular Materials as Efficient Catalysts for Advanced Coupling Reaction

Publication Name: Handbook of Materials Science, Volume 3
Publication Date: 2025
DOI: 10.1007/978-981-96-8229-4_16

Using Chloro-Substituted Difluoroalkylating Reagents

Publication Name: Science of Synthesis
Publication Date: 2025

From Bromo-Substituted Difluoroalkylating Reagents under Nickel Catalysis

Publication Name: Science of Synthesis
Publication Date: 2025