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Product Information

Product Name
Potassium iodide, 99+% (ACS)
Brand Name
US-Strem
Product Number
19-3200
CAS
7681-11-0
Certificate of Analysis (COA)​
COA not found

Description

Product Introduction

Potassium Iodide (KI) is a highly water-soluble inorganic salt composed of potassium cations (K⁺) and iodide anions (I⁻). It is typically supplied as a white crystalline solid and dissolves readily in water.

Because of its high iodide content, good water solubility, and relatively simple ionic composition, Potassium Iodide is an important reagent for iodide-based chemical reactions, analytical procedures, materials synthesis, and photovoltaic research.

High-purity grades are available for applications requiring strict control of trace-metal impurities. For example, electronic/materials research grades can reach ≥99.99% trace-metals basis, while ultra-high-purity grades are available at 99.995%.

 

Mechanism / Principle

Ionic Dissociation

In water, Potassium Iodide dissociates readily:

KI → K⁺ + I⁻

The resulting iodide ions participate in a variety of chemical and coordination processes.

Iodide as a Nucleophile and Reducing Species

Iodide can participate in substitution reactions and can also interact with oxidizing species. This makes Potassium Iodide useful in:

  • Organic synthesis
  • Redox chemistry
  • Iodometric analysis
  • Halide exchange reactions
  • Analytical chemistry

Halide Engineering in Materials

In perovskite materials, iodide ions can participate in halide-related equilibria and influence the composition and defect chemistry of the perovskite lattice.

Potassium Iodide has therefore been investigated as an additive for perovskite solar cells and light-emitting diodes, where K⁺ and I⁻ can contribute to defect passivation and improved material/device properties.

 

Key Research Applications

 

1. Perovskite Solar Cells

Potassium Iodide is an important additive investigated in perovskite photovoltaic research.

Applications include:

  • Perovskite precursor formulations
  • Perovskite film engineering
  • Defect passivation
  • Grain-boundary modification
  • Ion-migration studies
  • Perovskite solar cells
  • Perovskite LEDs

Research-grade KI can be used to introduce both K⁺ and I⁻ into perovskite precursor or post-treatment systems. Supplier information specifically identifies KI as an additive used to improve the stability and performance of perovskite solar cells and LEDs.

 

2. Organic Synthesis

Potassium Iodide is widely used as an iodide source in synthetic chemistry.

Applications include:

  • Halide exchange reactions
  • Nucleophilic substitution
  • Alkyl iodide preparation
  • Finkelstein-type reactions
  • Organic reaction development

 

3. Analytical Chemistry

Potassium Iodide is an important reagent in analytical chemistry.

Applications include:

  • Iodometric titration
  • Redox analysis
  • Oxidant determination
  • Iodine generation
  • Analytical reagent preparation

 

4. Biochemistry

Potassium Iodide can be used as a reagent in biochemical research.

Applications include:

  • Protein research
  • Nucleic-acid-related experiments
  • Chemical analysis
  • Solution preparation
  • Laboratory reagent formulations

 

5. Fluorescence Research

Iodide ions can act as collisional fluorescence quenchers.

Potassium Iodide is therefore used in fluorescence-related research to investigate:

  • Fluorescence quenching
  • Molecular interactions
  • Fluorescence mechanisms
  • Photophysical properties

Thermo Fisher specifically lists Potassium Iodide as a fluorescence quenching agent and also notes its use in the isolation of single-stranded DNA.

 

6. Semiconductor and Materials Research

High-purity Potassium Iodide can be used when low levels of metallic impurities are required.

Applications include:

  • Materials synthesis
  • Electronic-material research
  • Halide-based materials
  • Surface chemistry
  • Semiconductor-related research

High-purity KI grades are available with tightly controlled trace-metal specifications.

 

Advantages

  • High water solubility
  • Readily available iodide source
  • Simple and well-defined inorganic composition
  • Useful reagent for iodide-based reactions
  • Suitable for analytical chemistry
  • Useful in redox and substitution chemistry
  • Applicable to perovskite materials research
  • Suitable for fluorescence quenching studies
  • High-purity grades available
  • Trace-metal-controlled grades available

 

Storage & Handling

  • Store in a tightly closed container.
  • Keep in a cool, dry and well-ventilated area.
  • Protect from excessive moisture.
  • Avoid contamination with incompatible chemicals.
  • Use clean and dry laboratory equipment.
  • Wear appropriate gloves, protective clothing, and eye protection.
  • Avoid unnecessary inhalation of dust.
  • Follow the product-specific SDS for detailed storage and disposal requirements.

Commercial high-purity KI products may specify storage at 2–30°C and provide detailed impurity specifications for trace-analysis applications.

 

Research Areas

Potassium Iodide (CAS No. 7681-11-0) is widely used in:

  • Organic chemistry
  • Analytical chemistry
  • Biochemistry
  • Materials science
  • Perovskite photovoltaics
  • Perovskite LEDs
  • Semiconductor research
  • Nanotechnology
  • Fluorescence research
  • Redox chemistry
  • Pharmaceutical research
  • Chemical synthesis

FAQ

Frequently Asked Questions (FAQ)

 

Q1: What is Potassium Iodide?

A: Potassium Iodide is an inorganic salt with CAS No. 7681-11-0, molecular formula KI, and molecular weight 166.00 g/mol.

 

Q2: What is Potassium Iodide used for?

A: Potassium Iodide is used as an iodide source, analytical reagent, synthetic reagent, fluorescence quencher, and materials additive, including applications in perovskite solar-cell research.

 

Q3: What is the molecular formula of Potassium Iodide?

A: The molecular formula is KI.

 

Q4: What is the molecular weight of Potassium Iodide?

A: The molecular weight is 166.00 g/mol. NIST reports 166.0028 g/mol.

 

Q5: Is Potassium Iodide soluble in water?

A: Yes. Potassium Iodide is highly soluble in water; commercial specifications report approximately 1,430 g/L at 25°C.

 

Q6: Is Potassium Iodide used in perovskite solar cells?

A: Yes. KI is used as an additive in perovskite solar-cell and perovskite LED research, where K⁺ and I⁻ can contribute to defect passivation and material stabilization.

 

Q7: Is Potassium Iodide used for fluorescence quenching?

A: Yes. Iodide ions can act as collisional fluorescence quenchers, and Potassium Iodide is used for fluorescence quenching studies.

 

Q8: What purity grades of Potassium Iodide are available?

A: Depending on the application, Potassium Iodide is available in ACS reagent, biochemical, trace-metal, and ultra-high-purity grades, including ≥99.0%, ≥99.99%, and 99.995% grades.