(R)-3-(tert-Butyl)-4-(2,6-dimethoxyphenyl)-2,2-dimethyl-2,3-dihydrobenzo[d][1,3]oxaphosphole, 97% (>99% ee)

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Sku SC15-6882_100_MG
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General Details
CAS #
SMILES
Chemical Purity
Molecular Formula C21H27O3P
Chemical Formula
Formula Weight 358.16
Reaction
Note
Physical Properties
Purity 97% (>99% ee)
Density
Melting Point
Boiling Point
Flash Point
Vapor Pressure
Surface Area
Pore Volume
Specific Rotation
Shipping & Stability
Safety Yes
Store Cold
Dry Ice
Alternative Product for Air Shipment
Export Limitations
Pyrophoric
Hygroscopic
Air Sensitive
Light Sensitive
Heat Sensitive
Moisture Sensitive
Odorous Material

Technical Notes: L igand used with
1.Palladium catalyst for asymmetric Suzuki-Miyaura cross-coupling reactions.
2.NickeI catalyst for asymmetric intramolecular/intermolecular reductive addition.
References:
1. Org. Lett. 2012, 14 , 2258 2261
2.J. Am. Chem. Soc., 2014, 136, 570- 573
3.Angew. Chem., Int. Ed. 2015, 54, 7144-7148
4.Adv. Synth. Catal. 2016, 358, 3522-3527
5.ACS Catal. 2018, 8, 10190-10209
6.Angew. Chem., Int. Ed. 2015, 54, 2520 -2524
7.Org. Chem. Front. 2015, 2, 1322-1325