(R)-(+)-1-[(R)-2-(2'-Di-3,5-xylylphosphinophenyl)ferrocenyl]ethyldi-3,5-xylylphosphine, min. 97%|26-1555|894771-28-9

(R)-(+)-1-[(R)-2-(2'-Di-3,5-xylylphosphinophenyl)ferrocenyl]ethyldi-3,5-xylylphosphine, min. 97%

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Sku SC26-1555_100_MG
US-Strem
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Product Information

Product Name
(R)-(+)-1-(R)-2-(2'-Di-3,5-xylylphosphinophenyl)ferrocenylethyldi-3,5-xylylphosphine, min. 97%
Brand Name
US-Strem
Product Number
26-1555
CAS
894771-28-9
Certificate of Analysis (COA)​
COA not found

General Information

PubChem CID
156009173
IUPAC Name
2-2-1-bis(3,5-dimethylphenyl)phosphanylethylcyclopentylphenyl-bis(3,5-dimethylphenyl)phosphane;cyclopentane;iron
InChI Key
QBRCUWAVMPIVFT-UHFFFAOYSA-N
SMILES
CC1=CC(=CC(=C1)P(C2=CC=CC=C2C3CCCC3C(C)P(C4=CC(=CC(=C4)C)C)C5=CC(=CC(=C5)C)C)C6=CC(=CC(=C6)C)C)C.C1CCCC1.Fe

Application

Technical Notes :
1. Ligand for Rh and Ru-catalzyed hydrogenation of alkenes and ketones.
2.Rh-catalyzed intermolecular 4+2j.
3.Enantioselective reductive coupling of 1,3-enynes to heterocyclic aromatic aldehydes andketones.
References:
1. (a) Adv. Synth. Catal., 2003, 345, 160. (b) Org. L ett., 2006, 8, 2413. 2.Angew. Chem., 2008, 120, 5904.
3. J. Am. Chem., 2006, 128, 16448.