CAS # | 113978-91-9 |
SMILES | |
Chemical Purity | |
Molecular Formula | [(C4H9)3PH]BF4ae |
Chemical Formula | |
Formula Weight | 290.13 |
Reaction | |
Note |
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Sku SC15-5990_1_G
US-Strem
General Details
Physical Properties
Purity | 99% |
Density | |
Melting Point | |
Boiling Point | |
Flash Point | |
Vapor Pressure | |
Surface Area | |
Pore Volume | |
Specific Rotation |
Shipping & Stability
Safety | Yes |
Store Cold | |
Dry Ice | |
Alternative Product for Air Shipment | |
Export Limitations | |
Pyrophoric | |
Hygroscopic | |
Air Sensitive | |
Light Sensitive | |
Heat Sensitive | |
Moisture Sensitive | |
Odorous Material |
Technical Notes:
1. Air-stable, non-pyrophoric precursor of the Tri-n-butylphosphine ligand which is used in a variety of catalytic processes.
2.Catalyst in Baylis-Hillman reactions.
3.Azide reductions.
4.Acylation of alcohols by anhydrides.
5.L igand for formate reduction of allyl carbonates.
6.Synthesis of aromatic nitriles via Pd C-H functionalization.
References:
1Org. L ett., 2001, 3, 4295.
2.Org. L ett., 2003, 5, 3391.
3.J. Am. Chem. Soc., 2007, 129, 15372.