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Tri-n-butylphosphonium tetrafluoroborate, 99%|15-5990|113978-91-9

Tri-n-butylphosphonium tetrafluoroborate, 99%

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Sku SC15-5990_1_G
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Product Information

Product Name
Tri-n-butylphosphonium tetrafluoroborate, 99%
Brand Name
US-Strem
Product Number
15-5990
CAS
113978-91-9
Certificate of Analysis (COA)​
COA not found

General Information

PubChem CID
11818592
IUPAC Name
tributylphosphanium tetrafluoroborate
InChI Key
NCHAZLRRIGGCER-UHFFFAOYSA-O
SMILES
B-(F)(F)(F)F.CCCCPH+(CCCC)CCCC

Description

Technical Notes:
1. Air-stable, non-pyrophoric precursor of the Tri-n-butylphosphine ligand which is used in a variety of catalytic processes.
2.Catalyst in Baylis-Hillman reactions.
3.Azide reductions.
4.Acylation of alcohols by anhydrides.
5.L igand for formate reduction of allyl carbonates.
6.Synthesis of aromatic nitriles via Pd C-H functionalization.
References:
1Org. L ett., 2001, 3, 4295.
2.Org. L ett., 2003, 5, 3391.
3.J. Am. Chem. Soc., 2007, 129, 15372.

References Data Source From Pubchem

Ionic conductivities of tributylphosphonium tetrafluoroborate
Publication Name: Electrochemistry
Publication Date: 2016
DOI: 10.1007/978-3-642-02723-9_246

Catalysis with Phosphonium Salts as Ligand Precursors
Publication Name: Science of Synthesis
Publication Date: 2009

The Morita–Baylis–Hillman Reaction Using Air-Stable Phosphine Reagents
Publication Name: Science of Synthesis
Publication Date: 2009