N-Phenyl-2-(dicyclohexylphosphino)pyrrole, 90% [cataCXium? PCy]

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Sku SC15-3610_2_G

Vendor: US-Strem

Product Information

Product Name

N-Phenyl-2-(dicyclohexylphosphino)pyrrole, 90% cataCXium? PCy

Brand Name

US-Strem

Product Number

15-3610

CAS

672937-60-9

Certificate of Analysis (COA)

COA not found

General Information

PubChem CID

12140166

IUPAC Name

dicyclohexyl-(1-phenylpyrrol-2-yl)phosphane

InChI Key

RVFZOTGUPNHVRA-UHFFFAOYSA-N

SMILES

C1CCC(CC1)P(C2CCCCC2)C3=CC=CN3C4=CC=CC=C4

Application

Technical Notes: 1.Useful ligand for the Ru-catalyzed amination of diols.
2.Direct amination of secondary alcohols with ammonia.
3.Amino-alcohol cyclization to lactams or cyclic amines .
References:
1.Chem. Sus. Chem., 2009, 2, 551.
2.Angew. Chem. Int. Ed., 2010, 49, 8130.
3.Angew. Chem. Int. Ed., 2010, 49, 8126. 4.Catal. Sci. Technol., 2014, 4, 47.

References

Recent Developments in the Direct Synthesis of Unprotected Primary Amines

Publication Name: Synthesis

Publication Date: 2016-12-16

DOI: 10.1055/s-0036-1588371

The scope and mechanism of palladium-catalysed Markovnikov alkoxycarbonylation of alkenes.

Publication Name: Nature Chemistry

Publication Date: 2016-09-05

DOI: 10.1038/nchem.2586

Reactions of Primary or Secondary Amines with Alcoholic Hydroxy Groups

Publication Name: Science of Synthesis

Publication Date: 2013

Reactions of Ammonia with Alcoholic Hydroxy Groups