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1-(2-Methoxyphenyl)-2-(dicyclohexylphosphino)pyrrole, min. 95% [cataCXium? POMeCy]|15-2980|672937-63-2

1-(2-Methoxyphenyl)-2-(dicyclohexylphosphino)pyrrole, min. 95% [cataCXium? POMeCy]

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Sku SC15-2980_500_MG
US-Strem
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Product Information

Product Name
1-(2-Methoxyphenyl)-2-(dicyclohexylphosphino)pyrrole, min. 95% cataCXium? POMeCy
Brand Name
US-Strem
Product Number
15-2980
CAS
672937-63-2
Certificate of Analysis (COA)​
COA not found

General Information

PubChem CID
53411820
IUPAC Name
dicyclohexyl-1-(2-methoxyphenyl)pyrrol-2-ylphosphane
InChI Key
JUZAKZRALSJLOV-UHFFFAOYSA-N
SMILES
COC1=CC=CC=C1N2C=CC=C2P(C3CCCCC3)C4CCCCC4

Description

Technical Notes:
1. Highly efficient ligand for the palladium-catalyzed Suzuki reaction using aryl chlorides.
2.Carbonylative Heck reaction of aryl bromides with vinyl ethers .
3.Double carbonylation of aryl halides to synthesize 5-arylfuranones.
References:
1.Chem. Commun., 2004, 38
2.Chem. Eur. J., 2012, 18, 4827
3.Chem. Eur. J., 2013, 19, 12959

References Data Source From Pubchem

Synthesis from Aryl Bromides, Carbon Monoxide, Vinyl Ethers, and Hydrazines
Publication Name: Science of Synthesis
Publication Date: 2017

The scope and mechanism of palladium-catalysed Markovnikov alkoxycarbonylation of alkenes.
Publication Name: Nature Chemistry
Publication Date: 2016-09-05
DOI: 10.1038/nchem.2586

Design and Development of Ligands for Palladium-Catalyzed Carbonylation Reactions
Publication Name: Synthesis
Publication Date: 2014-06-10
DOI: 10.1055/s-0033-1338635

Synthesis of 5-Arylfuranones via a Carbonylative Heck Reaction
Publication Name: Synfacts
Publication Date: 2013-12-13
DOI: 10.1055/s-0033-1340423

The Recent Development of Phosphine Ligands Derived from 2-Phosphino-Substituted Heterocycles and Their Applications in Palladium-Catalyzed Cross-Coupling Reactions
Publication Name: Synlett
Publication Date: 2012-04-26
DOI: 10.1055/s-0031-1290672