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Sku SC15-1787_250_MG
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General Details
CAS # 1173836-08-2
SMILES
Chemical Purity
Molecular Formula C38H30N3P
Chemical Formula
Formula Weight 559.64
Reaction
Note
Physical Properties
Purity min. 97%
Density
Melting Point
Boiling Point
Flash Point
Vapor Pressure
Surface Area
Pore Volume
Specific Rotation
Shipping & Stability
Safety Yes
Store Cold
Dry Ice
Alternative Product for Air Shipment
Export Limitations
Pyrophoric
Hygroscopic
Air Sensitive
Light Sensitive
Heat Sensitive
Moisture Sensitive
Odorous Material

Technical Notes:
1. The PINAP family of P,N ligands is a synthetically more accessible but a similarly performing analog of the QUINAP (15-1777, 15-1778) ligand in enantioselective hydroboration, alkyne addition, and azomethine cycloaddition reactions. (Ref. 1)
2.With copper, enantioselective addition of alkynes to aldehydes to synthesize propargylamines .
3.With copper, catalytic, enantioselective, conjugate alkyne addition in aqueous media.
References:
1.Angew. Chem. Int. Ed.. 2004, 43, 5971. 2.Org. Lott 2006.8, 2437.
3.J. Am. Chom. Soc.2005, 127. 9682.