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Sku SC15-1786_1_G
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General Details
CAS # 828927-96-4
SMILES
Chemical Purity
Molecular Formula C38H30N3P
Chemical Formula
Formula Weight 559.64
Reaction
Note
Physical Properties
Purity min. 97%
Density
Melting Point
Boiling Point
Flash Point
Vapor Pressure
Surface Area
Pore Volume
Specific Rotation
Shipping & Stability
Safety Yes
Store Cold
Dry Ice
Alternative Product for Air Shipment
Export Limitations
Pyrophoric
Hygroscopic
Air Sensitive
Light Sensitive
Heat Sensitive
Moisture Sensitive
Odorous Material

Technical Notes:
1.. The PINAP family of P,N ligands is a synthetically more accessible but a similarly performing analog of the QUINAP (15-1777, 15-1778) ligand in enantioselective hydroboration, alkyne addition, and azomethine cycloaddition reactions. (Ref. 1)
2. With copper, enantioselective addition of alkynes to aldehydes to synthesize propargylamines.
3.With copper, catalytic, enantioselective, conjugate alkyne addition in aqueous media.
References:
1.Angew. Chem. Int. Ed., 2004, 43, 5971.
2.Org. L ett 2006, 8, 2437
3.J. Am. Chem. Soc., 2005, 127, 9682.