(R)-(+)-2-(Diphenylphosphino)-2'-methoxy-1,1'-binaphthyl, 99% (R)-MOP

(R)-(+)-2-(Diphenylphosphino)-2'-methoxy-1,1'-binaphthyl, 99% (R)-MOP

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Sku SC15-1775_500_MG
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General Details
Product Number 15-1775
CAS # 145964-33-6
Molecular Formula C33H25OP
Formula Weight 468.53
Physical Properties
Purity 99%
Shipping & Stability
Safety Yes

Technical Notes:
1. Efficient catalyst for the e nantioselective hydrosilyation of 1 -alkenes to optically active 2-alcohols.
2.Ligand for palladium-catalyzed asymmetric reduction of allylic esters ,
3: L igand for the rhodium catalyzed asymmetric arylation of imines with organostannanes .
4. L igand for the rhodium-catalyzed asymmetric addition of aryl- and alkenylboronic acids to Isatins.
5. Ligand for desymmetrization of malonamides via an enantioselective intramolecular Buchwald-Hartwig reaction.
References:
1. J. Am. Chem. Soc.. 1991, 1 13, 9887.
2.Acc. Chem. Res., 2000, 33, 354. (review) . 3.J. Am. Chem. Soc., 1994, 116, 775.
4. J. Am. Chem. Soc., 2000, 122, 976. 5.Angew. Chem. Int. Ed.. 2006, 45, 3353. 6. Tetrahedron L ett., 2009, 50, 41 70