(3aR,8aR)-(-)-4,4,8,8-Tetrakis(3,5-dimethylphenyl)tetrahydro-2,2-dimethyl-6-phenyl-1,3-dioxolo[4,5-e]dioxaphosphepin

Technical Notes:
1. Chiral ligand used in the nickel-catalyzed, enantioselective, conjugate allylation of activated enones.
2. Chiral ligand used in the palladium-catalyzed, enantioselective diboration of terminal alkenes.
3. Chiral ligand used in the palladium-catalyzed, asymmetric, 1 ,4-dihydroxylation of 1,3-dienes via catalytic enantioselectivediboration.
4. Chiral ligand used in the palladium-catalyzed diboration of N-silyated imines.
References:
1. J. Am. Chem. Soc.. 2008, 130, 4978. 2.J. Am. Chem. Soc.. 2009, 131, 13210. 3.J. Am. Chem. Soc.. 2009, 131, 9134. 4.J. Am. Chem. Soc.. 2013, 135, 9252. 5.Nature, 2014, 505, 386.