(11bR)-8,9,10,11,12,13,14,15-Octahydro-4-hydroxy-2,6-di-2-naphthalenyl-4-oxide-dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin, 98%, (99% ee)

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Sku SC15-1378_25_MG
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General Details
CAS # 922711-75-9
SMILES
Chemical Purity
Molecular Formula C40H33O4P
Chemical Formula
Formula Weight 608.7
Reaction
Note
Physical Properties
Purity 98%, (99% ee)
Density
Melting Point
Boiling Point
Flash Point
Vapor Pressure
Surface Area
Pore Volume
Specific Rotation
Shipping & Stability
Safety Yes
Store Cold
Dry Ice
Alternative Product for Air Shipment
Export Limitations
Pyrophoric
Hygroscopic
Air Sensitive
Light Sensitive
Heat Sensitive
Moisture Sensitive
Odorous Material

Technical Notes:
1.The preparation of binaphthol monophosphoric acid derivatives.
2.Organocatalyst developed for the diastereo- and enantioselective 1 4-conjugate addn. of a variety of
ß-ketoesters to nitroolefins, employed in the addn. re action, providing the corre sponding nitroalkanes in high yield (up to 97%) with moderate diastereoselectivities (up to 2.6:1 dr) and enantioselectivities (up to 58% ee).
References: 1.JP 4725757, EP 1038877, US 6274745, 2000-3-21. 2. Lett. in Org. Chem., 2010, 7, 219-225.