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Sku SC15-1364_100_MG
US-Strem
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Product Information

Product Name
(11aS)-10,11,12,13-Tetrahydro-5-hydroxy-3,7-di-9-phenanthrenyl-5-oxide-diindeno7,1-de:1',7'-fg1,3,2dioxaphosphocin, min. 98%
Brand Name
US-Strem
Product Number
15-1364
CAS
1585988-92-6
Certificate of Analysis (COA)​
COA not found

General Information

PubChem CID
57341905
IUPAC Name
12-hydroxy-1,10-di(phenanthren-9-yl)-4,5,6,7-tetrahydroiindeno7,1-de:1',7'-fg1,3,2dioxaphosphocine 12-oxide
InChI Key
GMCOBEDKNDREBU-UHFFFAOYSA-N
SMILES
C1CC23CCC4=C2C(=C(C=C4)C5=CC6=CC=CC=C6C7=CC=CC=C75)OP(=O)(OC8=C(C=CC1=C38)C9=CC1=CC=CC=C1C1=CC=CC=C19)O

Application

Technical Note:
1. Chiral Bronsted, acid-catalyzed, enantioselective F riedel-Crafts reaction of 2-methoxyfuran with aliphatic ketimines generated
in situ.
Reference:
1. Chem. Sci., 2016, 7, 1057.

References

Atroposelective Friedländer Annulation

Publication Name: Science of Synthesis
Publication Date: 2022