(11bR)-2,6-Bis[3,5-bis(1,1-dimethylethyl)-4-methoxyphenyl]-4-hydroxy-4-oxide-dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin, 98% (99% ee)|15-0554|957790-93-1

(11bR)-2,6-Bis[3,5-bis(1,1-dimethylethyl)-4-methoxyphenyl]-4-hydroxy-4-oxide-dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin, 98% (99% ee)

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Sku SC15-0554_50_MG
US-Strem
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Product Information

Product Name
(11bR)-2,6-Bis3,5-bis(1,1-dimethylethyl)-4-methoxyphenyl-4-hydroxy-4-oxide-dinaphtho2,1-d:1',2'-f1,3,2dioxaphosphepin, 98% (99% ee)
Brand Name
US-Strem
Product Number
15-0554
CAS
957790-93-1
Certificate of Analysis (COA)​
COA not found

General Information

PubChem CID
56930870
IUPAC Name
10,16-bis(3,5-ditert-butyl-4-methoxyphenyl)-13-hydroxy-12,14-dioxa-13λ5-phosphapentacyclo13.8.0.02,11.03,8.018,23tricosa-1(15),2(11),3,5,7,9,16,18,20,22-decaene 13-oxide
InChI Key
BRFHWVKCVFCDNX-UHFFFAOYSA-N
SMILES
CC(C)(C)C1=CC(=CC(=C1OC)C(C)(C)C)C2=CC3=CC=CC=C3C4=C2OP(=O)(OC5=C4C6=CC=CC=C6C=C5C7=CC(=C(C(=C7)C(C)(C)C)OC)C(C)(C)C)O

References

Enantioselective Biginelli Reaction of Aliphatic Aldehydes Catalyzed by a Chiral Phosphoric Acid: A Key Step in the Synthesis of the Bicyclic Guanidine Core of Crambescin A and Batzelladine A
Publication Name: Synthesis
Publication Date: 2018-04-25
DOI: 10.1055/s-0036-1591567

Highly Enantioselective Biginelli Reaction of Aliphatic Aldehydes Catalyzed by Chiral Phosphoric Acids
Publication Name: Synlett
Publication Date: 2017-06-27
DOI: 10.1055/s-0036-1588853|10.1055/s-0036-1589504