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Sku SC15-0127_100_MG
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General Details
CAS # 1107608-80-9
SMILES
Chemical Purity
Molecular Formula C18H28N2P2
Chemical Formula
Formula Weight 334.38
Reaction
Note
Physical Properties
Purity min. 98%
Density
Melting Point
Boiling Point
Flash Point
Vapor Pressure
Surface Area
Pore Volume
Specific Rotation
Shipping & Stability
Safety Yes
Store Cold
Dry Ice
Alternative Product for Air Shipment
Export Limitations
Pyrophoric
Hygroscopic
Air Sensitive
Light Sensitive
Heat Sensitive
Moisture Sensitive
Odorous Material

Technical Notes:
1. Ligand for the rhodium catalyzed, asymmetric hydrogenation of dehydroamino acid esters and a enamides
2.Ligand for the rhodium-catalyzed, asymmetric 1 ,4-addition of arylboronic acids to a,ß-unsaturated carbonyI compounds.
3. Ligand for the rhodium catalyzed, asymmetric alkylative ring opening reaction
4. Ligand for the palladium-catalyzed asymmetric allylic alkylation and amination of racemic substrates.
5.Ligand for the ruthe niumcatalyzed asymmetric hydrogenation of ketones.
6. Ligand for the rhodium-catalyzed, asymmetric hydroacylation of 1, 1-disubstituted alkenes with aldehydes.
References:
1.J. Am. chem. Soc., 2005, 127, 11934.
2.J. Org. Chem., 2007, 72,7413.
3.J. Am. Chem. Soc., 2009, 131, 12552.
4.J. Am. C hem. Soc., 2009, 132, 5328.