(S)-(-)-5,5',6,6'-Tetramethyl-3,3'-di-t-butyl-1,1'-biphenyl-2,2'-diol, 99% (S)-BIPHEN H2|08-2047|205927-03-3

(S)-(-)-5,5',6,6'-Tetramethyl-3,3'-di-t-butyl-1,1'-biphenyl-2,2'-diol, 99% (S)-BIPHEN H2

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Sku SC08-2047_500_MG
US-Strem
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Product Information

Product Name
(S)-(-)-5,5',6,6'-Tetramethyl-3,3'-di-t-butyl-1,1'-biphenyl-2,2'-diol, 99% (S)-BIPHEN H2
Brand Name
US-Strem
Product Number
08-2047
CAS
205927-03-3
Certificate of Analysis (COA)​
COA not found

General Information

PubChem CID
3255344
IUPAC Name
6-tert-butyl-2-(3-tert-butyl-2-hydroxy-5,6-dimethylphenyl)-3,4-dimethylphenol
InChI Key
NMVVBVMYPLMIOU-UHFFFAOYSA-N
SMILES
CC1=CC(=C(C(=C1C)C2=C(C(=CC(=C2O)C(C)(C)C)C)C)O)C(C)(C)C

Application

Technical Notes:
1. High enantiose lectivity in iridium-catalyzed asymmetric hydrogenation.
2. Kinetic resolution of planar-chiral (n6- arene chromium complexes by molybdenum-catalyzed asymmetric ring- closing metathesis.
3.Palladium(l)/Bronsted acid-catalyzed enantioselective oxidative carbocycliization-borylation of enallenes.
4. Branch-selective and enantioselective hydroarylation of alkenes via anilide-directed c -H oxidative addition using iridium as a catalyst

References Data Source From Pubchem

Recent Developments in Transition-Metal-Catalyzed Asymmetric Hydrogenation of Enamides
Publication Name: Synthesis
Publication Date: 2020-10-20
DOI: 10.1055/s-0040-1705939

Rare-earth metal catalysts for alkene hydrosilylation
Publication Name: Science China Chemistry
Publication Date: 2019-02-22
DOI: 10.1007/s11426-018-9403-7

Transition-Metal-Free Enantioselective Reactions of Organo­magnesium Reagents Mediated by Chiral Ligands
Publication Name: Synthesis
Publication Date: 2018-06-20
DOI: 10.1055/s-0037-1610135

Asymmetric Allylic Substitution Catalyzed by Pd−Thioether−Phosphite
Publication Name: Synfacts
Publication Date: 2014-06-16
DOI: 10.1055/s-0034-1378269

From Isolated Homoleptic Complexes
Publication Name: Science of Synthesis
Publication Date: 2013