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2-[(4S)-4-tert-Butyl-4,5-dihydro-2-oxazolyl]-4-(trifluoromethyl)pyridine, 98%|07-1050|1257527-14-2

2-[(4S)-4-tert-Butyl-4,5-dihydro-2-oxazolyl]-4-(trifluoromethyl)pyridine, 98%

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Sku SC07-1050_100_MG
US-Strem
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Product Information

Product Name
2-(4S)-4-tert-Butyl-4,5-dihydro-2-oxazolyl-4-(trifluoromethyl)pyridine, 98%
Brand Name
US-Strem
Product Number
07-1050
CAS
1257527-14-2
Certificate of Analysis (COA)​
COA not found

General Information

PubChem CID
97182182
IUPAC Name
(4S)-4-tert-butyl-2-4-(trifluoromethyl)-2-pyridinyl-4,5-dihydro-1,3-oxazole
InChI Key
ALYKOKFCPJUMPB-SNVBAGLBSA-N
SMILES
CC(C)(C)C@H1COC(=N1)C2=NC=CC(=C2)C(F)(F)F

Safety Information

Storage Condition
Store at 2-8℃

Description

Technical Notes:
1.Ligand used in enantioselective Pd-catalyzed alkene difunctionalization reaction .
2.Ligand used in enantioselective Heck arylations of acyclic alkenyI alcohols .
3.Ligand for enantios electiv Pd-catalyzed conjugate addition of arylboronic acids to ß-substituted cyclic enones .
References:
1.J. Am. Chem. Soc. 2010, 132, 17471.
2.Science 2012, 338, 1455.
3.J. Am. Chem. Soc.2013, 135, 14996.

References Data Source From Pubchem

4-Selective Pyridine Functionalization Reactions via Heterocyclic Phosphonium Salts
Publication Name: Synlett
Publication Date: 2017-12-12
DOI: 10.1055/s-0036-1591850

Kinetic Resolution of 5-Substituted Cyclohexenols by Palladium-Catalyzed Asymmetric Redox-Relay Heck Reaction
Publication Name: Synthesis
Publication Date: 2016-09-09
DOI: 10.1055/s-0035-1562620