Cat. No JK528432_100_G
J&K Chemical

Product Information

Product Name
N,N'-Diphenyl-p-phenylenediamine, 95%
Brand Name
J&K
Product Number
528432
CAS
74-31-7
Molecular Formula
C18H16N2
Molecular Weight
260.34
SDS Document
Certificate of Analysis (COA)​
COA not found

General Information

PubChem CID
6319
IUPAC Name
1-N,4-N-diphenylbenzene-1,4-diamine
InChI Key
UTGQNNCQYDRXCH-UHFFFAOYSA-N
SMILES
C1=CC=C(C=C1)NC2=CC=C(C=C2)NC3=CC=CC=C3

Properties

Melting Point
143-145
Boiling Point
220-225

Safety Information

Signal Word
Warning
Hazard Statement
H317
H412
Precautionary Statement
P261
P272
P280
P321
P501
P273
P302+P352
P333+P317
P362+P364

Application

Product Introduction

N,N'-Diphenyl-p-phenylenediamine (DPPD) is a high-performance amine-based antioxidant and rubber antidegradant widely used in rubber, elastomers, plastics, petroleum products, polymer systems, and industrial formulations.

As a member of the p-phenylenediamine (PPD) antioxidant family, DPPD provides effective protection against thermal oxidation, oxygen aging, flex cracking, ozone attack, and metal-catalyzed degradation in organic materials. It is commonly applied in natural rubber, synthetic rubber, latex systems, and polymer stabilization applications.

Due to its strong antioxidative performance and durability enhancement capabilities, DPPD is widely used in rubber compounding, polymer additive development, and industrial materials stabilization.

Chemical Properties and Reaction Mechanism

N,N'-Diphenyl-p-phenylenediamine functions primarily as a secondary amine antioxidant, free-radical scavenger, and anti-aging stabilizer.

In oxidation systems:

  • Scavenges oxygen-centered radicals and peroxy radicals
  • Interrupts autoxidative chain reactions
  • Helps suppress heat-, oxygen-, and ozone-induced degradation
  • Reduces deterioration caused by copper and transition-metal contamination 

Key stabilization features:

  • Aromatic p-phenylenediamine antioxidant structure
  • Strong resistance to thermal and oxidative aging
  • Effective protection against flex fatigue and cracking
  • Good compatibility with various rubber systems

Its multifunctional antioxidant mechanism makes it valuable for long-term polymer durability applications.

Key Research Applications

1.Rubber and Elastomer Stabilization

DPPD is widely used in rubber antioxidant systems.

Typical applications include:

  • Natural rubber (NR) stabilization
  • Styrene-butadiene rubber (SBR) protection
  • Nitrile rubber (NBR) antioxidant formulations
  • Chloroprene and synthetic elastomer stabilization

2.Anti-Aging and Oxidation Control Research

Useful in material durability studies.

Applications include:

  • Thermal aging resistance evaluation
  • Oxidative degradation inhibition studies
  • Flex cracking resistance research
  • Ozone and environmental aging studies

3.Polymer and Industrial Materials Research

The compound is commonly used in polymer stabilization systems.

Applications include:

  • Plastics stabilization studies
  • Polymer processing protection
  • Engineering material durability evaluation
  • Additive performance optimization

4.Petroleum and Specialty Chemical Applications

Widely used in industrial formulation research.

Applications include:

  • Petroleum oil stabilization
  • Polymerization inhibition studies
  • Specialty additive development
  • Chemical intermediate applications

Recommended Experimental Conditions

Parameter Recommended Conditions
Application Type Rubber antioxidant / polymer stabilizer
Formulation Systems Rubber, elastomers, plastics, oils
Processing Conditions Polymer compounding and stabilization systems
Usage Level Optimize according to formulation requirements
Blending Strategy Standalone or synergistic antioxidant systems

Recommended dosage should be optimized based on polymer type, environmental exposure, and processing conditions.

Advantages in Stabilization Applications

  • Highly effective amine antioxidant and antidegradant
  • Strong protection against thermal and oxidative aging
  • Good resistance to flex cracking and ozone deterioration
  • Effective in natural and synthetic rubber systems
    • Suitable for industrial polymer stabilization applications

Storage & Handling

Store in a cool place. Keep container tightly closed in a dry and well ventilated place.

Containers which are opened must be carefully resealed and kept upright to prevent leakage.

Research Areas

Researchers working in the following fields may benefit from this compound:

  • Rubber and elastomer chemistry
  • Polymer stabilization research
  • Industrial additive formulation science
  • Materials aging and durability studies
  • Petroleum and specialty chemical applications

FAQ

Frequently Asked Questions (FAQ)

 

What is N,N'-Diphenyl-p-phenylenediamine used for?
It is widely used as a rubber antioxidant, polymer stabilizer, and anti-aging additive in elastomers, plastics, and industrial formulations.

 

How does DPPD protect polymers and rubber materials?
It functions by scavenging radicals, interrupting oxidation chain reactions, and suppressing oxidative and thermal degradation.

 

Which rubber systems commonly use DPPD?
Typical systems include NR, SBR, NBR, chloroprene rubber, and synthetic elastomer compounds.

 

Can DPPD help improve resistance to flex cracking and aging?
Yes, it is widely recognized for enhancing thermal aging resistance, flex durability, and anti-degradation performance.

 

Is DPPD compatible with other stabilizers?
Yes, it can be used together with secondary antioxidants, rubber protective additives, and stabilizer packages depending on formulation design.

 

Does antioxidant performance depend on formulation conditions?
Yes, parameters such as substrate type, dosage level, processing temperature, and additive compatibility may affect final stabilization performance.

References

Occurrence and environmental fate/behaviors of tire wear particles and their human and ecological health: an emerging global issue

Publication Name: Archives of Toxicology
Publication Date: 2025-08-16
DOI: 10.1007/s00204-025-04147-4

Impacts of Water and Antioxidants on the Storage Stability of Microalgae Biodiesel: An Experimental Study

Publication Name: Microbial Niche Nexus Sustaining Environmental Biological Wastewater and Water-Energy-Environment Nexus
Publication Date: 2025
DOI: 10.1007/978-3-031-62660-9_16

Nanofillers in Additives for Rubber and Tire Industry

Publication Name: Handbook of Nanofillers
Publication Date: 2025
DOI: 10.1007/978-981-96-2407-2_94

Aromatic Cross-Conjugated Hydrazones as Inhibitors of the Radical Chain Oxidation of Styrene

Publication Name: Kinetics and Catalysis
Publication Date: 2024-10
DOI: 10.1134/s0023158424601852

N,N'-Diphenyl-p-phenylenediamine, 95%

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