Spiro aromatic compounds are an important class of building blocks for organic semiconductors. Their unique orthogonal spiro-conjugated architecture, rigid three-dimensional configuration, and intrinsic steric hindrance effectively improve the optoelectronic properties, thermal stability, and morphological stability of organic electronic materials.
Among them, Spirofluorene-9,9'-xanthene (SFX) has emerged as a next-generation spiro scaffold owing to its efficient one-pot synthetic methodology, which significantly simplifies the preparation process compared with conventional spirobifluorene derivatives while reducing production cost. As a versatile molecular platform, SFX-based intermediates have attracted extensive attention in the development of OLED materials, organic lasers, organic field-effect transistors (OFETs), perovskite solar cells (PSCs), and other advanced optoelectronic devices.
2,7-Dibromospirofluorene-9,9'-xanthene features two reactive bromine atoms that enable further functionalization through Suzuki–Miyaura, Stille, Negishi, Kumada, and other palladium-catalyzed cross-coupling reactions, making it an excellent intermediate for constructing high-performance π-conjugated materials.
Left:2D-GIXD Pattern of a Py-SFDBAO Nanosheet Film Right:Proposed Molecular Packing Arrangement of Py-SFDBAO on a Si Substrate
Features & Benefits
Improves the quantum efficiency of OLED and other optoelectronic devices
Enhances thermal, morphological, and photochemical stability of organic semiconductor materials
Product Information Product Name 2,7-Dibromospirofluorene-9,7'-dibenzoc,hacridine, 95% Brand Name J&K Product Number 9001833 CAS 1303969-21-2 Molecular Formula C33H19Br2N Molecular Weight 589.32 Certificate of Analysis (COA) Search COA not found General Information...
Product Information Product Name 2',7'-Dibromospirofluorene-9,9'-xanthene, 95% Brand Name J&K Product Number 9001820 CAS 1346002-88-7 Molecular Formula C25H14Br2O Molecular Weight 490.19 Certificate of Analysis (COA) Search COA not found General Information...
Product Information Product Name 2,2',7,7'-Tetrabromospirofluorene-9,9'-xanthene, 95% Brand Name J&K Product Number 9001821 CAS 1338596-81-8 Molecular Formula C25H12Br4O Molecular Weight 647.98 Certificate of Analysis (COA) Search COA not found General Information...
Product Information Product Name 3'-Bromospirofluorene-9,9'-xanthene, 90% Brand Name J&K Product Number 9001822 CAS 1621397-55-4 Molecular Formula C25H15BrO Molecular Weight 411.29 Certificate of Analysis (COA) Search COA not found General Information...
Product Information Product Name N2,N2,N7,N7-Tetraphenyloxiranefluorene-9,9'-oxanthene-2,7-diamine, 95% Brand Name J&K Product Number 9001824 CAS 1160862-06-5 Molecular Formula C49H34N2O Molecular Weight 666.81 Certificate of Analysis (COA) Search COA not found General Information...
Product Information Product Name Spirofluorene-9,9'-xanthen-2-yl-diphenyl phosphine oxide, 98% Brand Name J&K Product Number 9001825 CAS 1346002-80-9 Molecular Formula C37H25O2P Molecular Weight 532.57 Certificate of Analysis (COA) Search COA not found...
Product Information Product Name Spirofluorene-9,9'-xanthen-2'-yl-diphenyl phosphine oxide, 95% Brand Name J&K Product Number 9001826 CAS 1346002-82-1 Molecular Formula C37H25O2P Molecular Weight 532.57 Certificate of Analysis (COA) Search COA not found...
Product Information Product Name Spirofluorene-9,9'-xanthene-2,7-diylbis(diphenylphosphine oxide), 95% Brand Name J&K Product Number 9001828 CAS 1346002-81-0 Molecular Formula C49H34O3P2 Molecular Weight 732.74 Certificate of Analysis (COA) Search COA not found General...