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US-Strem
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Product Information

Product Name
Lithium chloride, 99% (ACS)
Brand Name
US-Strem
Product Number
93-0313
CAS
7447-41-8
Certificate of Analysis (COA)​
COA not found

General Information

PubChem CID
433294
IUPAC Name
lithium chloride
InChI Key
KWGKDLIKAYFUFQ-UHFFFAOYSA-M
SMILES
Li+.Cl-

Application

Product Introduction

Lithium Chloride (LiCl, CAS No. 7447-41-8) is an important lithium-containing inorganic salt widely used in battery materials, electrolyte research, chemical synthesis, humidity control, analytical chemistry, pharmaceuticals, and advanced materials development. It is one of the most commonly used lithium compounds due to its high solubility, excellent ionic conductivity, and strong affinity for water.

Lithium chloride serves as a key raw material for lithium-based chemical production and is extensively investigated in lithium-ion battery technologies, solid-state electrolytes, molten salt systems, and electrochemical applications. Its unique physicochemical properties also make it valuable in organic synthesis, catalysis, and laboratory research.

Chemical Information

Property Value
Chemical Name Lithium Chloride
Synonyms Lithium Chloride Anhydrous; LiCl
CAS Number 7447-41-8
Molecular Formula LiCl
Molecular Weight 42.39 g/mol
Appearance White crystalline powder or crystals
Melting Point ~605°C
Boiling Point ~1382°C
Solubility Highly soluble in water
Storage Room temperature, dry conditions

 

 

Chemical Characteristics

Lithium Chloride exhibits several important properties:

  • Highly water soluble lithium salt
  • Strong hygroscopicity and moisture absorption capability
  • Excellent ionic conductivity
  • Stable inorganic lithium source
  • Compatible with electrochemical systems
  • Useful precursor for lithium-containing materials

 

Key Research Applications

1. Battery Materials & Electrochemical Research

Lithium chloride is widely used as a lithium source and additive in energy storage research.

Typical applications include:

  • Lithium-ion battery material synthesis
  • Solid-state electrolyte research
  • Lithium salt preparation
  • Electrochemical interface studies
  • Battery performance optimization

LiCl can provide lithium ions during material preparation and is studied as an additive in electrolyte and electrode systems.

 

2. Solid-State Battery Research

Due to its lithium-ion conductivity and compatibility with inorganic materials, lithium chloride is used in solid-state battery development.

Typical applications include:

  • Lithium-containing ceramic synthesis
  • Solid electrolyte preparation
  • Ion conduction studies
  • Interface engineering
  • Next-generation battery research

 

3. Organic Synthesis & Chemical Research

Lithium chloride is frequently used as a reagent or additive in synthetic chemistry.

Typical applications include:

  • Carbonyl compound synthesis
  • Organolithium chemistry
  • Reaction medium modification
  • Selective transformations
  • Catalyst-assisted synthesis

 

4. Analytical Chemistry

Lithium chloride is widely used in analytical and laboratory applications.

Typical applications include:

  • Lithium ion standards
  • Ion chromatography analysis
  • Chemical reference materials
  • Laboratory reagent preparation
  • Quality control testing

 

5. Humidity Control & Industrial Applications

Due to its strong hygroscopic properties, LiCl is widely used for moisture-related applications.

Typical applications include:

  • Humidity sensors
  • Moisture calibration
  • Desiccant systems
  • Air conditioning research
  • Environmental monitoring

 

6. Pharmaceutical & Biomedical Research

Lithium chloride is used as a research reagent in biological and biochemical studies.

Typical applications include:

  • Cell signaling research
  • Enzyme regulation studies
  • Molecular biology research
  • Biochemical pathway investigation

 

Recommended Experimental Conditions

Parameter Recommended Conditions
Storage Temperature Room temperature
Atmosphere Dry environment recommended
Moisture Protection Required
Solvent Water, polar solvents
Handling Avoid prolonged exposure to humid air

Advantages

  • High-purity lithium source
  • Excellent water solubility
  • Strong ionic conductivity
  • Widely used in lithium chemistry
  • Suitable for battery material development
  • Useful in analytical and synthetic chemistry
  • Stable inorganic reagent

 

Storage & Handling

  • Store in a tightly sealed container.
  • Protect from moisture because lithium chloride is highly hygroscopic.
  • Keep in a dry environment.
  • Avoid contact with strong acids and incompatible materials.
  • Use appropriate laboratory protective equipment.

 

Research Areas

  • Lithium-ion batteries
  • Solid-state batteries
  • Electrochemistry
  • Battery materials
  • Organic synthesis
  • Analytical chemistry
  • Materials science
  • Chemical research
  • Energy storage technology

FAQ

What is Lithium Chloride (LiCl) used for?

Lithium Chloride is widely used as a lithium source, electrolyte-related material, chemical reagent, humidity control agent, and analytical standard in research and industrial applications.

 

Why is Lithium Chloride important for battery research?

LiCl provides lithium ions and is used in the preparation and investigation of lithium-containing materials, electrolytes, and solid-state battery components.

 

Is Lithium Chloride used in solid-state batteries?

Yes. Lithium chloride is investigated as a component or additive in lithium-containing solid electrolytes and battery interface studies.

 

Why is Lithium Chloride highly hygroscopic?

The Li⁺ ion has strong hydration ability, allowing lithium chloride to readily absorb moisture from the environment.

 

Can Lithium Chloride be used in organic synthesis?

Yes. LiCl is frequently used as a reagent or additive to modify reaction conditions and improve selectivity in synthetic chemistry.

 

How should Lithium Chloride be stored?

Store Lithium Chloride in a sealed container under dry conditions. Because it readily absorbs moisture, exposure to humid air should be minimized.

 

Is this product intended for research use only?

Yes. This product is supplied for laboratory research, analytical testing, battery material development, and industrial R&D applications only.

References Data Source From Pubchem

Waste per- and polyfluoroalkyl substance-assisted flash fluorination for lithium recovery from brine

Publication Name: Nature Water
Publication Date: 2026-03-10
DOI: 10.1038/s44221-026-00593-1

Pathogen-free atmospheric water harvesting using a mussel-inspired wet-adhesive photothermal aerogel

Publication Name: Nature Water
Publication Date: 2026-03-06
DOI: 10.1038/s44221-026-00592-2

From air to safe water

Publication Name: Nature Water
Publication Date: 2026-03-06
DOI: 10.1038/s44221-026-00599-9

Spontaneous uranium extraction from salt-lake water via droplet falling

Publication Name: Nature Sustainability
Publication Date: 2026-03-05
DOI: 10.1038/s41893-026-01781-3

A solvent-in-salt method for optoelectronic perovskite synthesis

Publication Name: Nature Synthesis
Publication Date: 2026-03-05
DOI: 10.1038/s44160-026-01020-9