(9S)-(9''S)-9,9''-[(2,5-diphenyl-4,6-pyrimidinediyl)bis(oxy)]bis[6'-methoxycinchonan], 98%, (99% de)|07-1428|1202521-49-0

(9S)-(9''S)-9,9''-[(2,5-diphenyl-4,6-pyrimidinediyl)bis(oxy)]bis[6'-methoxycinchonan], 98%, (99% de)

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Sku SC07-1428_250_MG
US-Strem
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Product Information

Product Name
(9S)-(9''S)-9,9''-(2,5-diphenyl-4,6-pyrimidinediyl)bis(oxy)bis6'-methoxycinchonan, 98%, (99% de)
Brand Name
US-Strem
Product Number
07-1428
CAS
1202521-49-0
Certificate of Analysis (COA)​
COA not found

General Information

PubChem CID
12193538
IUPAC Name
4-(S)-(2R,4S,5R)-5-ethenyl-1-azabicyclo2.2.2octan-2-yl-6-(S)-(2R,4S,5R)-5-ethenyl-1-azabicyclo2.2.2octan-2-yl-(6-methoxyquinolin-4-yl)methoxy-2,5-diphenylpyrimidin-4-yloxymethyl-6-methoxyquinoline
InChI Key
KLZPTMFWYYUEKH-DOGDSVMGSA-N
SMILES
COC1=CC2=C(C=CN=C2C=C1)C@@H(C@H3CC@@H4CCN3CC@@H4C=C)OC5=C(C(=NC(=N5)C6=CC=CC=C6)OC@H(C@H7CC@@H8CCN7CC@@H8C=C)C9=C1C=C(C=CC1=NC=C9)OC)C1=CC=CC=C1

Application

Technical Notes：
1. Used in asymmetric construction of quaternary stereocenters by direct organocatalytic amination of 3- substituted oxindoles.
2. Catalyst for asymmetric Michael addition of unprotected 3 -substituted oxindoles to 1 ,4-naphthoquinone .
References:
1.Chem. Commun., 2009, 6753.
2.Beilstein J. Org. Chem. 2012, 8, 1360.