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Sku SC07-1413_100_MG
US-Strem
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Product Information

Product Name
2,6-Bis(4R,5S)-4,5-dihydro-4,5-diphenyl-2-oxazolyl Pyridine, 98%
Brand Name
US-Strem
Product Number
07-1413
CAS
497172-36-8
Certificate of Analysis (COA)​
COA not found

General Information

PubChem CID
11845876
IUPAC Name
(4R,5S)-2-6-(4R,5S)-4,5-diphenyl-4,5-dihydro-1,3-oxazol-2-yl-2-pyridinyl-4,5-diphenyl-4,5-dihydro-1,3-oxazole
InChI Key
SMYDLHVQRYQCDL-FYZVQMPESA-N
SMILES
C1=CC=C(C=C1)C@@H2C@@H(OC(=N2)C3=NC(=CC=C3)C4=NC@@H(C@@H(O4)C5=CC=CC=C5)C6=CC=CC=C6)C7=CC=CC=C7

Application

Technical Notes:
1.Pybox ligand used in Ce-catalyzed enantioselective nitrone cycloadditions of a,ß-unsaturated 2-acylimidazoles.
2.L igand for the enantioselective Cu-catalyzed propargylic amination.
3.Ligand for the Cu-catalyzed intermolecular asymmetric propargylic dearomatization of indoles .
4.Ligand for the Pd-catalyzed asymmetric aminohydroxylation of 1,3-dienes.
5.Used in the synthesis of N-alkylated 4-pyridones by Cu-catalyzed intermolecular asymmetric propargylicamination.
6.Ligand for the Cu-catalyzed asymmetric propargylation of indolizines .
7.Ligand for the metal catalyzed asymme tric dias te reodivergent Michael addition of 2-chloromalonate esters to conjugated imines.

References Data Source From Pubchem

Domino Reactions of Tertiary Enamides in Organic Synthesis

Publication Name: Synlett
Publication Date: 2021-02-02
DOI: 10.1055/a-1352-6358

Tertiary Enamides as Versatile and Valuable Substrates to Reach Chemical Diversity

Publication Name: Synthesis
Publication Date: 2020-05-18
DOI: 10.1055/s-0040-1707403

Recent Advances in Catalytic Transformations Involving Copper Acetylides

Publication Name: Synthesis
Publication Date: 2017-01-24
DOI: 10.1055/s-0036-1588405

Copper-Catalyzed Oxidation of Alkenes and Heterocycles

Publication Name: Synthesis
Publication Date: 2016-06-15
DOI: 10.1055/s-0035-1561649

Copper-Catalyzed Asymmetric Synthesis of Pyrrolo[2,1-a]isoquinolines

Publication Name: Synfacts
Publication Date: 2016-04-18
DOI: 10.1055/s-0035-1562052