(4,4'-Di-t-butyl-2,2'-bipyridine)bis[3,5-difluoro-2-[5-trifluoromethyl-2-pyridinyl-kN)phenyl-kC]iridium(III) hexafluorophosphate, 99%|77-0425|870987-63-6

(4,4'-Di-t-butyl-2,2'-bipyridine)bis[3,5-difluoro-2-[5-trifluoromethyl-2-pyridinyl-kN)phenyl-kC]iridium(III) hexafluorophosphate, 99%

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Sku SC77-0425_50_MG
US-Strem
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Product Information

Product Name
(4,4'-Di-t-butyl-2,2'-bipyridine)bis3,5-difluoro-2-5-trifluoromethyl-2-pyridinyl-kN)phenyl-kCiridium(III) hexafluorophosphate, 99%
Brand Name
US-Strem
Product Number
77-0425
CAS
870987-63-6
Certificate of Analysis (COA)​
COA not found

General Information

PubChem CID
53260182
IUPAC Name
4-tert-butyl-2-(4-tert-butyl-2-pyridinyl)pyridine;bis(2-(2,4-difluorobenzene-6-id-1-yl)-5-(trifluoromethyl)pyridine);iridium(3+);hexafluorophosphate
InChI Key
XFAXYKCDJPDUTA-UHFFFAOYSA-N
SMILES
CC(C)(C)C1=CC(=NC=C1)C2=NC=CC(=C2)C(C)(C)C.C1=CC(=NC=C1C(F)(F)F)C2=C(C=C(C=C-2)F)F.C1=CC(=NC=C1C(F)(F)F)C2=C(C=C(C=C-2)F)F.FP-(F)(F)(F)(F)F.Ir+3

Application

Technical Notes:
1.Visible light photoredox-catalyzed cascade cyclizations of a-bromochalcones or a-bromocinnamates with heteroarenes . 2.Enantioselective a-benzylation of aldehydes via photoredox organocatalysis.
References:
1.Adv. Synth. Cat., 2014, 356, 557 .
2. J. Amer. Chem. Soc., 2010, 132, 13600.

References Data Source From Pubchem

Reactions with Alkynes
Publication Name: Science of Synthesis
Publication Date: 2026

Reactions with Bicyclo[1.1.0]butanes
Publication Name: Science of Synthesis
Publication Date: 2026

Reactions with Ketones
Publication Name: Science of Synthesis
Publication Date: 2026

Photosensitized Reduction of Arenes
Publication Name: Science of Synthesis
Publication Date: 2026

Reactions with Vinylcyclopropanes
Publication Name: Science of Synthesis
Publication Date: 2026