racemic-Di-tert-butyl(3-(tert-butyl)-4-(dimethylamino)-2,3-dihydrobenzo[d][1,3]oxaphosphol-2-yl)phosphine oxide, 97%|15-6330|1788085-47-1

racemic-Di-tert-butyl(3-(tert-butyl)-4-(dimethylamino)-2,3-dihydrobenzo[d][1,3]oxaphosphol-2-yl)phosphine oxide, 97%

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Sku SC15-6330_100_MG
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Product Information

Product Name
racemic-Di-tert-butyl(3-(tert-butyl)-4-(dimethylamino)-2,3-dihydrobenzod1,3oxaphosphol-2-yl)phosphine oxide, 97%
Brand Name
US-Strem
Product Number
15-6330
CAS
1788085-47-1
Certificate of Analysis (COA)​
COA not found

General Information

PubChem CID
132850091
IUPAC Name
(2S,3S)-3-tert-butyl-2-ditert-butylphosphoryl-N,N-dimethyl-2H-1,3-benzoxaphosphol-4-amine
InChI Key
TUYVJJFLJWCOEY-BVZFJXPGSA-N
SMILES
CC(C)(C)P@@1C@H(OC2=CC=CC(=C21)N(C)C)P(=O)(C(C)(C)C)C(C)(C)C

Application

Technical Notes:
1.Ligand/palladium catalyst for aryl-alkyl Suzuki-Miyaura cross-coupling reactions with ArBr. 2. Ligand/palladium catalyst for aryl-alkyl Suzuki-Miyaura cross-coupling reactions with ArOTf.
References:
1.Angew. Chem., Int. Ed. 2015, 54, 3792-3796.
2.Org. Biomol. Chem., 2017, 15, 9903-9909.

References Data Source From Pubchem

Addressing the Challenges in Suzuki–Miyaura Cross-Couplings by Ligand Design
Publication Name: Synlett
Publication Date: 2016-06-23
DOI: 10.1055/s-0035-1562360