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Sku SC15-6320_250_MG
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Product Information

Product Name
(S)-1-(3-(tert-Butyl)-2,3-dihydrobenzod1,3oxaphosphol-4-yl)-2,5-diphenyl-1H-pyrrole, 97% (>99% ee)
Brand Name
US-Strem
Product Number
15-6320
CAS
1683581-58-9
Certificate of Analysis (COA)​
COA not found

General Information

PubChem CID
132850092
IUPAC Name
1-(3S)-3-tert-butyl-2H-1,3-benzoxaphosphol-4-yl-2,5-diphenylpyrrole
InChI Key
KJXNLTFQUPGVAM-SSEXGKCCSA-N
SMILES
CC(C)(C)P@@1COC2=CC=CC(=C21)N3C(=CC=C3C4=CC=CC=C4)C5=CC=CC=C5

Application

Technical Notes:
1.Ligand/palladium catalyst for dearomative cyclization
2.Ligand/palladium catalyst for cyclization
3.Ligand/palladium catalyst for Suzuki-Miyaura cross-coupling reactions.
4.Ligand/nickel catalyst for asymmetric intramolecular/intremolecular reductive cyclization
5.Ligand/palladium catalyst for asymmetric cyclization

References Data Source From Pubchem

Catalytic Enantioselective Friedel–Crafts Reactions of Naphthols and Electron-Rich Phenols

Publication Name: Synthesis
Publication Date: 2016-04-20
DOI: 10.1055/s-0035-1561434

Palladium-Catalyzed Enantioselective Dearomative Cyclization of Phenols

Publication Name: Synfacts
Publication Date: 2015-03-18
DOI: 10.1055/s-0034-1380394