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Sku SC15-6290_250_MG
US-Strem
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Product Information

Product Name
(R)-3-(tert-Butyl)-4-(2,3,5,6-tetrahydrobenzo1,2-b:5,4-b'difuran-8-yl)-2,3-dihydrobenzod1,3oxaphosphole, 97% (>99% ee)
Brand Name
US-Strem
Product Number
15-6290
CAS
1835717-07-1
Certificate of Analysis (COA)​
COA not found

General Information

PubChem CID
145710261
IUPAC Name
(3R)-3-tert-butyl-4-(2,3,5,6-tetrahydrofuro3,2-f1benzofuran-8-yl)-2H-1,3-benzoxaphosphole
InChI Key
HVBRAPIYTGCMEN-VWLOTQADSA-N
SMILES
CC(C)(C)P@1COC2=CC=CC(=C21)C3=C4C(=CC5=C3OCC5)CCO4

Application

Technical Notes:
1.Ligand/palladium catalyst for general Suzuki-Miyaura borylation reactions.
2.Ligand/palladium catalyst for Cyclization
3.Ligand/palladium catalyst for general and sterically demanding Suzuki-Miyaura cross-coupling reactions .
4.Ligand/palladium catalyst for sterically demanding Buchwald-Hartwig amination.
5.Ligand/palladium catalyst for asymmetric Suzuki-Miyaura cross-coupling reactions.
6.Ligand/nickel catalyst for asymmetric intramolecular/intremolecular reductive cyclization
7.Ligand/rhodium catalyst for asymmetric hydroboration

References Data Source From Pubchem

State-of-the-Art Advances in Enantioselective Transition-Metal-Mediated Reactions of Silacyclobutanes

Publication Name: Synthesis
Publication Date: 2022-09-21
DOI: 10.1055/a-1929-4890

Synthesis of P- and S-Stereogenic Compounds via Enantioselective C–H Functionalization

Publication Name: Synthesis
Publication Date: 2022-05-12
DOI: 10.1055/a-1802-6793

Nickel-Catalyzed Enantioselective α-Alkenylation of N-Sulfonyl Amines

Publication Name: Synfacts
Publication Date: 2021-05-18
DOI: 10.1055/s-0040-1720637