(2S,2'S,3S,3'S)-3,3'-Di-tert-butyl-4,4'-diphenyl-2,2',3,3'-tetrahydro-2,2'-bibenzo[d][1,3]oxaphosphole, 97% (>99% ee) (2S,2'S,3S,3'S)-Ph-BIBOP|15-6265|1202033-21-3

(2S,2'S,3S,3'S)-3,3'-Di-tert-butyl-4,4'-diphenyl-2,2',3,3'-tetrahydro-2,2'-bibenzo[d][1,3]oxaphosphole, 97% (>99% ee) (2S,2'S,3S,3'S)-Ph-BIBOP

$338.00

FREE
SHIPPING

100% MONEY
BACK GUARANTEE

ONLINE
SUPPORT 24/7

Available on backorder. No lead time available. Please request a quote.
Sku SC15-6265_100_MG
US-Strem
Get Bulk Quote

Product Information

Product Name
(2S,2'S,3S,3'S)-3,3'-Di-tert-butyl-4,4'-diphenyl-2,2',3,3'-tetrahydro-2,2'-bibenzod1,3oxaphosphole, 97% (>99% ee) (2S,2'S,3S,3'S)-Ph-BIBOP
Brand Name
US-Strem
Product Number
15-6265
CAS
1202033-21-3
Certificate of Analysis (COA)​
COA not found

General Information

PubChem CID
70925931
IUPAC Name
(2S,3S)-3-tert-butyl-2-(2S,3S)-3-tert-butyl-4-phenyl-2H-1,3-benzoxaphosphol-2-yl-4-phenyl-2H-1,3-benzoxaphosphole
InChI Key
PXMPZIBJGLMMQU-BHBXGUOQSA-N
SMILES
CC(C)(C)P@@1C@H(OC2=CC=CC(=C21)C3=CC=CC=C3)C@H4OC5=CC=CC(=C5P@@4C(C)(C)C)C6=CC=CC=C6

Application

Technical Notes:
1. Ligand/Rhodium catalyst for asymmetric hydrogenation of enamides.
2. Ligand/Rhodium catalyst for asymmetric arylboronic reagents addition to aryl ketones
References:
1.Angew. Chem., Int. Ed. 2013, 52, 4235. 2.Angew. Chem., Int. Ed. 2016, 55, 4527.
3.Adv. Syn. Cat. 2013, 355, 1297 .