(2R,2'R,3R,3'R)-3,3'-Di-tert-butyl-4,4'-diphenyl-2,2',3,3'-tetrahydro-2,2'-bibenzo[d][1,3]oxaphosphole, 97% (>99% ee) (2R,2'R,3R,3'R)-Ph-BIBOP|15-6260|2719857-97-1

(2R,2'R,3R,3'R)-3,3'-Di-tert-butyl-4,4'-diphenyl-2,2',3,3'-tetrahydro-2,2'-bibenzo[d][1,3]oxaphosphole, 97% (>99% ee) (2R,2'R,3R,3'R)-Ph-BIBOP

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Product Information

Product Name
(2R,2'R,3R,3'R)-3,3'-Di-tert-butyl-4,4'-diphenyl-2,2',3,3'-tetrahydro-2,2'-bibenzod1,3oxaphosphole, 97% (>99% ee) (2R,2'R,3R,3'R)-Ph-BIBOP
Brand Name
US-Strem
Product Number
15-6260
CAS
2719857-97-1
Certificate of Analysis (COA)​
COA not found

General Information

PubChem CID
138375946
IUPAC Name
(2R,3R)-3-tert-butyl-2-(2R,3R)-3-tert-butyl-4-phenyl-2H-1,3-benzoxaphosphol-2-yl-4-phenyl-2H-1,3-benzoxaphosphole
InChI Key
PXMPZIBJGLMMQU-IWIDZHLOSA-N
SMILES
CC(C)(C)P@1C@@H(OC2=CC=CC(=C21)C3=CC=CC=C3)C@@H4OC5=CC=CC(=C5P@4C(C)(C)C)C6=CC=CC=C6

Application

Technical Notes:
1. Ligand/Rhodium catalyst for asymmetric hydrogenation of enamides.
2. Ligand/Rhodium catalyst for asymmetric arylboronic reagents addition to aryl ketones
References:
1.Angew. Chem., Int. Ed. 2013, 52, 4235. 2.Angew. Chem., Int. Ed. 2016, 55, 4527.
3.Adv. Syn. Cat. 2013, 355, 1297 .