(2S,2'S,3S,3'S)-3,3'-Di-tert-butyl-4,4'-dimethoxy-2,2',3,3'-tetrahydro-2,2'-bibenzo[d][1,3]oxaphosphole, 97% (>99% ee) (2S,2'S,3S,3'S)-MeO-BIBOP|15-6255|1202033-19-9

(2S,2'S,3S,3'S)-3,3'-Di-tert-butyl-4,4'-dimethoxy-2,2',3,3'-tetrahydro-2,2'-bibenzo[d][1,3]oxaphosphole, 97% (>99% ee) (2S,2'S,3S,3'S)-MeO-BIBOP

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Product Information

Product Name
(2S,2'S,3S,3'S)-3,3'-Di-tert-butyl-4,4'-dimethoxy-2,2',3,3'-tetrahydro-2,2'-bibenzod1,3oxaphosphole, 97% (>99% ee) (2S,2'S,3S,3'S)-MeO-BIBOP
Brand Name
US-Strem
Product Number
15-6255
CAS
1202033-19-9
Certificate of Analysis (COA)​
COA not found

General Information

PubChem CID
70925994
IUPAC Name
(2S,3S)-3-tert-butyl-2-(2S,3S)-3-tert-butyl-4-methoxy-2H-1,3-benzoxaphosphol-2-yl-4-methoxy-2H-1,3-benzoxaphosphole
InChI Key
KVPCVNGTJXEQKH-OBMDHMNCSA-N
SMILES
CC(C)(C)P@@1C@H(OC2=C1C(=CC=C2)OC)C@H3OC4=C(P@@3C(C)(C)C)C(=CC=C4)OC

Application

Technical Notes:
1. Ligand/Rhodium catalyst for asymmetric hydrogenation of enamides .
2.Ligand/Rhodium catalyst for asymmetric arylboronic reagents addition to aryl ketones 3.Ligand/Copper catalyst for asymmetric addition.
4. Ligand/Rhodium catalyst for asymmetric hydrogenation.
5. Ligand/Rhodium catalyst for asymmetric hydroformylation.

References Data Source From Pubchem

Catalytic Asymmetric Synthesis of P-Stereogenic Phosphines: Beyond Precious Metals
Publication Name: Synlett
Publication Date: 2020-10-13
DOI: 10.1055/s-0040-1707309

Search for Ideal P-Chiral Phosphorus Ligands for Practical Asymmetric Hydrogenation and Asymmetric Suzuki–Miyaura Coupling
Publication Name: Synlett
Publication Date: 2013-09-23
DOI: 10.1055/s-0033-1339875